Structure and Magnetic Properties of Mixed-Ligand Complexes of 3d Metal Hexafluoroacetylacetonates with 3,5- and 3,6-Di-Tert-Butyl-O-Benzoquinones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2020-04

AUTHORS

S. V. Fokin, E. Yu. Fursova, G. A. Letyagin, A. S. Bogomyakov, V. A. Morozov, G. V. Romanenko, V. I. Ovcharenko

ABSTRACT

The reaction of metal hexafluoroacetylacetonates M(hfac)2, where M = Fe, Mn, and Co, with 3,6-di-tert-butyl-o-benzoquinone (3,6-Q) in the inert atmosphere of a dry box is found to yield mixed-ligand complexes [M(hfac)2(3,6-Q)]. When the synthesis is performed under ambient conditions or the [M(hfac)2(3,6-Q)] mother liquor is kept in air in the case of Mn(II) and Co(II), crystals of [M(hfac)2(H2O)2](3,6-Q) aqua complexes precipitate into the solid phase, in which cis-coordinated H2O molecules are hydrogen bonded to o-quinone O atoms. Single crystal X-ray diffraction data for compounds, which correlate with the results of quantum chemical calculations, show that solid [M(hfac)2(3,6-Q)] and [M(hfac)2(H2O)2](3,6-Q), where M = Co(II) and Mn(II), contain initial o-quinone molecules. In the interaction of Fe(hfac)2 with 3,6-Q, there is an intramolecular redox process during which Fe(II) is oxidized to Fe(III) and o-quinone is reduced to the respective semiquinonate radical anion, which leads to the formation of [FeIII(hfac)2(3,6-SQ)]. According to the data of magnetic measurements, a strong antiferromagnetic exchange between high-spin Fe(III) unpaired electrons and SQ provide an almost complete compensation of spin of one of the unpaired electrons of the metal ion by SQ spin. For Co a complex with 3,5-di-tert-butyl-o-benzoquinone [Co(hfac)2(3,5-Q)] is also synthesized and its structure and magnetic properties are studied. The latter prove to be similar to those of [Co(hfac)2(3,6-Q)]. More... »

PAGES

541-549

References to SciGraph publications

  • 2019-10. Thermoinduced Structural Transformations of [Fe(hfac)2(THF)2] in JOURNAL OF STRUCTURAL CHEMISTRY
  • 2016-02-15. Designed metalloprotein stabilizes a semiquinone radical in NATURE CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s002247662004006x

    DOI

    http://dx.doi.org/10.1134/s002247662004006x

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1129739189


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Inorganic Chemistry", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Physical Chemistry (incl. Structural)", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.419389.e", 
              "name": [
                "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Fokin", 
            "givenName": "S. V.", 
            "id": "sg:person.01124231331.57", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01124231331.57"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.419389.e", 
              "name": [
                "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Fursova", 
            "givenName": "E. Yu.", 
            "id": "sg:person.07501453217.49", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Novosibirsk State University, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4605.7", 
              "name": [
                "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
                "Novosibirsk State University, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Letyagin", 
            "givenName": "G. A.", 
            "id": "sg:person.015022712237.87", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015022712237.87"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Novosibirsk State University, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4605.7", 
              "name": [
                "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
                "Novosibirsk State University, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Bogomyakov", 
            "givenName": "A. S.", 
            "id": "sg:person.0776526105.71", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776526105.71"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Novosibirsk State University, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4605.7", 
              "name": [
                "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
                "Novosibirsk State University, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Morozov", 
            "givenName": "V. A.", 
            "id": "sg:person.01031430247.14", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01031430247.14"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.419389.e", 
              "name": [
                "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Romanenko", 
            "givenName": "G. V.", 
            "id": "sg:person.0664032236.40", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.419389.e", 
              "name": [
                "International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Ovcharenko", 
            "givenName": "V. I.", 
            "id": "sg:person.0732145436.56", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1134/s0022476619100081", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1122330962", 
              "https://doi.org/10.1134/s0022476619100081"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1038/nchem.2453", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040175226", 
              "https://doi.org/10.1038/nchem.2453"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2020-04", 
        "datePublishedReg": "2020-04-01", 
        "description": "The reaction of metal hexafluoroacetylacetonates M(hfac)2, where M = Fe, Mn, and Co, with 3,6-di-tert-butyl-o-benzoquinone (3,6-Q) in the inert atmosphere of a dry box is found to yield mixed-ligand complexes [M(hfac)2(3,6-Q)]. When the synthesis is performed under ambient conditions or the [M(hfac)2(3,6-Q)] mother liquor is kept in air in the case of Mn(II) and Co(II), crystals of [M(hfac)2(H2O)2](3,6-Q) aqua complexes precipitate into the solid phase, in which cis-coordinated H2O molecules are hydrogen bonded to o-quinone O atoms. Single crystal X-ray diffraction data for compounds, which correlate with the results of quantum chemical calculations, show that solid [M(hfac)2(3,6-Q)] and [M(hfac)2(H2O)2](3,6-Q), where M = Co(II) and Mn(II), contain initial o-quinone molecules. In the interaction of Fe(hfac)2 with 3,6-Q, there is an intramolecular redox process during which Fe(II) is oxidized to Fe(III) and o-quinone is reduced to the respective semiquinonate radical anion, which leads to the formation of [FeIII(hfac)2(3,6-SQ)]. According to the data of magnetic measurements, a strong antiferromagnetic exchange between high-spin Fe(III) unpaired electrons and SQ provide an almost complete compensation of spin of one of the unpaired electrons of the metal ion by SQ spin. For Co a complex with 3,5-di-tert-butyl-o-benzoquinone [Co(hfac)2(3,5-Q)] is also synthesized and its structure and magnetic properties are studied. The latter prove to be similar to those of [Co(hfac)2(3,6-Q)].", 
        "genre": "article", 
        "id": "sg:pub.10.1134/s002247662004006x", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isFundedItemOf": [
          {
            "id": "sg:grant.8726747", 
            "type": "MonetaryGrant"
          }
        ], 
        "isPartOf": [
          {
            "id": "sg:journal.1135923", 
            "issn": [
              "0022-4766", 
              "2542-0976"
            ], 
            "name": "Journal of Structural Chemistry", 
            "publisher": "Pleiades Publishing", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "4", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "61"
          }
        ], 
        "keywords": [
          "mixed ligand complexes", 
          "metal hexafluoroacetylacetonates", 
          "quantum chemical calculations", 
          "single crystal X", 
          "intramolecular redox process", 
          "strong antiferromagnetic exchange", 
          "quinone O atoms", 
          "magnetic properties", 
          "aqua complexes", 
          "chemical calculations", 
          "crystal X", 
          "redox processes", 
          "radical anion", 
          "ray diffraction data", 
          "quinone molecules", 
          "metal ions", 
          "H2O molecules", 
          "unpaired electron", 
          "di-tert", 
          "O atoms", 
          "inert atmosphere", 
          "mother liquor", 
          "antiferromagnetic exchange", 
          "magnetic measurements", 
          "ambient conditions", 
          "dry box", 
          "hexafluoroacetylacetonate", 
          "diffraction data", 
          "solid phase", 
          "electrons", 
          "complexes", 
          "spin", 
          "butyl", 
          "molecules", 
          "CO", 
          "complete compensation", 
          "anions", 
          "benzoquinone", 
          "properties", 
          "ions", 
          "atoms", 
          "compounds", 
          "synthesis", 
          "hydrogen", 
          "structure", 
          "quinone", 
          "reaction", 
          "crystals", 
          "calculations", 
          "Fe", 
          "atmosphere", 
          "Mn", 
          "measurements", 
          "liquor", 
          "formation", 
          "air", 
          "interaction", 
          "phase", 
          "sq", 
          "exchange", 
          "compensation", 
          "process", 
          "conditions", 
          "data", 
          "results", 
          "box", 
          "cases", 
          "cis-coordinated H2O molecules", 
          "respective semiquinonate radical anion", 
          "semiquinonate radical anion", 
          "SQ spin"
        ], 
        "name": "Structure and Magnetic Properties of Mixed-Ligand Complexes of 3d Metal Hexafluoroacetylacetonates with 3,5- and 3,6-Di-Tert-Butyl-O-Benzoquinones", 
        "pagination": "541-549", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1129739189"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1134/s002247662004006x"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1134/s002247662004006x", 
          "https://app.dimensions.ai/details/publication/pub.1129739189"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-01-01T18:57", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_866.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1134/s002247662004006x"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s002247662004006x'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s002247662004006x'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s002247662004006x'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s002247662004006x'


     

    This table displays all metadata directly associated to this object as RDF triples.

    189 TRIPLES      22 PREDICATES      100 URIs      89 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1134/s002247662004006x schema:about anzsrc-for:03
    2 anzsrc-for:0302
    3 anzsrc-for:0306
    4 schema:author N47e89fe0ba61468ba98093d8ee67f0a7
    5 schema:citation sg:pub.10.1038/nchem.2453
    6 sg:pub.10.1134/s0022476619100081
    7 schema:datePublished 2020-04
    8 schema:datePublishedReg 2020-04-01
    9 schema:description The reaction of metal hexafluoroacetylacetonates M(hfac)2, where M = Fe, Mn, and Co, with 3,6-di-tert-butyl-o-benzoquinone (3,6-Q) in the inert atmosphere of a dry box is found to yield mixed-ligand complexes [M(hfac)2(3,6-Q)]. When the synthesis is performed under ambient conditions or the [M(hfac)2(3,6-Q)] mother liquor is kept in air in the case of Mn(II) and Co(II), crystals of [M(hfac)2(H2O)2](3,6-Q) aqua complexes precipitate into the solid phase, in which cis-coordinated H2O molecules are hydrogen bonded to o-quinone O atoms. Single crystal X-ray diffraction data for compounds, which correlate with the results of quantum chemical calculations, show that solid [M(hfac)2(3,6-Q)] and [M(hfac)2(H2O)2](3,6-Q), where M = Co(II) and Mn(II), contain initial o-quinone molecules. In the interaction of Fe(hfac)2 with 3,6-Q, there is an intramolecular redox process during which Fe(II) is oxidized to Fe(III) and o-quinone is reduced to the respective semiquinonate radical anion, which leads to the formation of [FeIII(hfac)2(3,6-SQ)]. According to the data of magnetic measurements, a strong antiferromagnetic exchange between high-spin Fe(III) unpaired electrons and SQ provide an almost complete compensation of spin of one of the unpaired electrons of the metal ion by SQ spin. For Co a complex with 3,5-di-tert-butyl-o-benzoquinone [Co(hfac)2(3,5-Q)] is also synthesized and its structure and magnetic properties are studied. The latter prove to be similar to those of [Co(hfac)2(3,6-Q)].
    10 schema:genre article
    11 schema:inLanguage en
    12 schema:isAccessibleForFree false
    13 schema:isPartOf N0eab5501c5a945bfb65a0035b6b7b2a1
    14 Nf0a5087071af4bbba2a80fd41306f78f
    15 sg:journal.1135923
    16 schema:keywords CO
    17 Fe
    18 H2O molecules
    19 Mn
    20 O atoms
    21 SQ spin
    22 air
    23 ambient conditions
    24 anions
    25 antiferromagnetic exchange
    26 aqua complexes
    27 atmosphere
    28 atoms
    29 benzoquinone
    30 box
    31 butyl
    32 calculations
    33 cases
    34 chemical calculations
    35 cis-coordinated H2O molecules
    36 compensation
    37 complete compensation
    38 complexes
    39 compounds
    40 conditions
    41 crystal X
    42 crystals
    43 data
    44 di-tert
    45 diffraction data
    46 dry box
    47 electrons
    48 exchange
    49 formation
    50 hexafluoroacetylacetonate
    51 hydrogen
    52 inert atmosphere
    53 interaction
    54 intramolecular redox process
    55 ions
    56 liquor
    57 magnetic measurements
    58 magnetic properties
    59 measurements
    60 metal hexafluoroacetylacetonates
    61 metal ions
    62 mixed ligand complexes
    63 molecules
    64 mother liquor
    65 phase
    66 process
    67 properties
    68 quantum chemical calculations
    69 quinone
    70 quinone O atoms
    71 quinone molecules
    72 radical anion
    73 ray diffraction data
    74 reaction
    75 redox processes
    76 respective semiquinonate radical anion
    77 results
    78 semiquinonate radical anion
    79 single crystal X
    80 solid phase
    81 spin
    82 sq
    83 strong antiferromagnetic exchange
    84 structure
    85 synthesis
    86 unpaired electron
    87 schema:name Structure and Magnetic Properties of Mixed-Ligand Complexes of 3d Metal Hexafluoroacetylacetonates with 3,5- and 3,6-Di-Tert-Butyl-O-Benzoquinones
    88 schema:pagination 541-549
    89 schema:productId Ncf89282cdb874a2b8bfaf4b24d14c297
    90 Nf5a4ef37616648efaad598d9ba917086
    91 schema:sameAs https://app.dimensions.ai/details/publication/pub.1129739189
    92 https://doi.org/10.1134/s002247662004006x
    93 schema:sdDatePublished 2022-01-01T18:57
    94 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    95 schema:sdPublisher N4496bbacc0484e4688b2e0938ddff2f3
    96 schema:url https://doi.org/10.1134/s002247662004006x
    97 sgo:license sg:explorer/license/
    98 sgo:sdDataset articles
    99 rdf:type schema:ScholarlyArticle
    100 N0eab5501c5a945bfb65a0035b6b7b2a1 schema:issueNumber 4
    101 rdf:type schema:PublicationIssue
    102 N23e0922277c0434c96e127154253e3ed rdf:first sg:person.0732145436.56
    103 rdf:rest rdf:nil
    104 N340ed3176bc74ff3b58a5b1b2c497608 rdf:first sg:person.07501453217.49
    105 rdf:rest N5859c1b44e1d4880a54f52f30136fdc5
    106 N4496bbacc0484e4688b2e0938ddff2f3 schema:name Springer Nature - SN SciGraph project
    107 rdf:type schema:Organization
    108 N47e89fe0ba61468ba98093d8ee67f0a7 rdf:first sg:person.01124231331.57
    109 rdf:rest N340ed3176bc74ff3b58a5b1b2c497608
    110 N5859c1b44e1d4880a54f52f30136fdc5 rdf:first sg:person.015022712237.87
    111 rdf:rest Nd644bc51e27543699af5386ebd068ed0
    112 N6be28affea69470e8f955cca33cad2d1 rdf:first sg:person.01031430247.14
    113 rdf:rest Nb435b43ee48d4a5c88cf4ae1581f7faa
    114 Nb435b43ee48d4a5c88cf4ae1581f7faa rdf:first sg:person.0664032236.40
    115 rdf:rest N23e0922277c0434c96e127154253e3ed
    116 Ncf89282cdb874a2b8bfaf4b24d14c297 schema:name dimensions_id
    117 schema:value pub.1129739189
    118 rdf:type schema:PropertyValue
    119 Nd644bc51e27543699af5386ebd068ed0 rdf:first sg:person.0776526105.71
    120 rdf:rest N6be28affea69470e8f955cca33cad2d1
    121 Nf0a5087071af4bbba2a80fd41306f78f schema:volumeNumber 61
    122 rdf:type schema:PublicationVolume
    123 Nf5a4ef37616648efaad598d9ba917086 schema:name doi
    124 schema:value 10.1134/s002247662004006x
    125 rdf:type schema:PropertyValue
    126 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    127 schema:name Chemical Sciences
    128 rdf:type schema:DefinedTerm
    129 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
    130 schema:name Inorganic Chemistry
    131 rdf:type schema:DefinedTerm
    132 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
    133 schema:name Physical Chemistry (incl. Structural)
    134 rdf:type schema:DefinedTerm
    135 sg:grant.8726747 http://pending.schema.org/fundedItem sg:pub.10.1134/s002247662004006x
    136 rdf:type schema:MonetaryGrant
    137 sg:journal.1135923 schema:issn 0022-4766
    138 2542-0976
    139 schema:name Journal of Structural Chemistry
    140 schema:publisher Pleiades Publishing
    141 rdf:type schema:Periodical
    142 sg:person.01031430247.14 schema:affiliation grid-institutes:grid.4605.7
    143 schema:familyName Morozov
    144 schema:givenName V. A.
    145 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01031430247.14
    146 rdf:type schema:Person
    147 sg:person.01124231331.57 schema:affiliation grid-institutes:grid.419389.e
    148 schema:familyName Fokin
    149 schema:givenName S. V.
    150 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01124231331.57
    151 rdf:type schema:Person
    152 sg:person.015022712237.87 schema:affiliation grid-institutes:grid.4605.7
    153 schema:familyName Letyagin
    154 schema:givenName G. A.
    155 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015022712237.87
    156 rdf:type schema:Person
    157 sg:person.0664032236.40 schema:affiliation grid-institutes:grid.419389.e
    158 schema:familyName Romanenko
    159 schema:givenName G. V.
    160 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40
    161 rdf:type schema:Person
    162 sg:person.0732145436.56 schema:affiliation grid-institutes:grid.419389.e
    163 schema:familyName Ovcharenko
    164 schema:givenName V. I.
    165 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56
    166 rdf:type schema:Person
    167 sg:person.07501453217.49 schema:affiliation grid-institutes:grid.419389.e
    168 schema:familyName Fursova
    169 schema:givenName E. Yu.
    170 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49
    171 rdf:type schema:Person
    172 sg:person.0776526105.71 schema:affiliation grid-institutes:grid.4605.7
    173 schema:familyName Bogomyakov
    174 schema:givenName A. S.
    175 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776526105.71
    176 rdf:type schema:Person
    177 sg:pub.10.1038/nchem.2453 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040175226
    178 https://doi.org/10.1038/nchem.2453
    179 rdf:type schema:CreativeWork
    180 sg:pub.10.1134/s0022476619100081 schema:sameAs https://app.dimensions.ai/details/publication/pub.1122330962
    181 https://doi.org/10.1134/s0022476619100081
    182 rdf:type schema:CreativeWork
    183 grid-institutes:grid.419389.e schema:alternateName International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
    184 schema:name International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
    185 rdf:type schema:Organization
    186 grid-institutes:grid.4605.7 schema:alternateName Novosibirsk State University, Novosibirsk, Russia
    187 schema:name International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
    188 Novosibirsk State University, Novosibirsk, Russia
    189 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...