Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-10

AUTHORS

S. S. Shapovalov, A. V. Kolos, A. P. Makhin, I. V. Skabitskii, N. P. Simonenko, V. V. Minin

ABSTRACT

In the interaction of norzooanemonin 1,3-dimethylimidazolium-4-carboxylate (1) with CuBr2, two types of crystals form: purple [Cu(L)2Br2][CuBr4][CuL4] (2) and light blue [CuL4][CuBr3] (3). In the reaction of 1 with CoCl2 in methanol, neutral complex Co(L)2Cl2 (4) forms. The thermal decomposition of complex 4 is studied. At the first stage of this decomposition, two equivalents of CO2 remove in a range 218–275 °C, and then a two-phase removal of two equivalents of L and the formation of CoCl2 occur. More... »

PAGES

1648-1654

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s002247661910010x

DOI

http://dx.doi.org/10.1134/s002247661910010x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1122329214


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