Structure and Magnetic Properties of Lanthanide Compounds with the 3,6-Di(Tert-Butyl)-1,2-Benzoquinone Radical Anion View Full Text


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Article Info

DATE

2019-07

AUTHORS

G. V. Romanenko, S. V. Fokin, G. A. Letyagin, A. S. Bogomyakov, V. I. Ovcharenko

ABSTRACT

Molecular and crystal structures of mononuclear lanthanide (Ln) compounds with the 3,6-di(tert-butyl)-1,2-benzoquinone (SQ) radical anion of the composition [Ln(SQ)3(THF)2] (Ln = Pr, Nd, Eu, Tb, Dy), [Ln(SQ)3(Q)], (Ln = Gd, Eu; Q – 3,6-di(tert-butyl)-1,2-benzoquinone), [La(SQ)3(Q)(THF)], [CeIV(SQ)4], [NaLn(SQ)4(THF)3]·0.25C6H14 (Ln = Gd, Tb), [NaLn(SQ)4(Q)(THF)] (Ln = La, Pr) are determined. The study of the magnetic properties of isolated heterospin solid phases reveals that intramolecular antiferromagnetic exchange interactions between unpaired electrons of SQ moieties dominate in them. At T≤2 K [Dy(SQ)3(THF)2] exhibits the properties typical of a metamagnetic compound. More... »

PAGES

1091-1100

References to SciGraph publications

  • 2004-01-01. Valence Tautomeric Transition Metal Complexes in SPIN CROSSOVER IN TRANSITION METAL COMPOUNDS II
  • 2018-01. Multinuclear compounds of s-elements with sterically hindered о-semiquinonates and catecholates in RUSSIAN CHEMICAL BULLETIN
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    http://scigraph.springernature.com/pub.10.1134/s0022476619070102

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    http://dx.doi.org/10.1134/s0022476619070102

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