Structural Manifestations of the Polarizability Effect in 1-Halogensilatranes According to the Dipole-Induced Dipole Mechanism View Full Text


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Article Info

DATE

2019-06

AUTHORS

S. N. Tandura, V. V. Belyaeva, V. P. Baryshok, B. A. Gostevsky, V. I. Smirnov

ABSTRACT

A new mechanism of the dipole-induced dipole polarizability effect by the example of 1-halogensilatranes is proposed. The mechanism involves a through-space interaction between the dipole moment μ of the core and the dipole Δμ which is induced on the halogen and, in turn, induces an extra dipole ΔΔμ on the transannular bond Si ← N to make it stronger. This effect explains for the first time the previously discovered contradiction for 1-halogensilatranes where an inverse dependence in the linear correlations between the Si ← N bond length, δ15N, δ1H(CH2N) chemical shifts, and the inductive constant σ are observed. For example, the length of the Si ← N coordination bond is shorter in 1-chlorosilatranе than in 1-fluorosilatrane due to the fact that the polarizability effect is stronger than the inductive effect in the case of the Cl atom. More... »

PAGES

932-941

References to SciGraph publications

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    http://scigraph.springernature.com/pub.10.1134/s0022476619060076

    DOI

    http://dx.doi.org/10.1134/s0022476619060076

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    https://app.dimensions.ai/details/publication/pub.1117769400


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