Transformation Of Magnetic Transitions and Crystal Structure of NdBaMn2O6 At Diamagnetic Dilution with Ti4+ Ions in the Mn-Sublattice View Full Text


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Article Info

DATE

2018-12

AUTHORS

E. V. Sterkhov, S. A. Uporov

ABSTRACT

Magnetic and structural transitions in NdBaMn2−xTixO6 (x = 0, 0.2) samples obtained by the topotactic procedure at 1373 K and lgPO2=−19 atm are studied by low-temperature X-ray diffraction and magnetometry in 1–5 T fields. Undoped double manganite undergoes a reversible ferromagnet—antiferromagnet magnetic phase transition at ТN = 278 K without changing symmetry. The 20 mol.% titanium substitution for manganese causes a decrease in symmetry from the tetragonal space group P4/mmm to the orthorhombic space group Pmmm and a shift of magnetic transitions to lower temperatures. Oxide NdBaMn2O6 demonstrates high values of the magnetocaloric effect in the temperature range 250–315 K. More... »

PAGES

2023-2028

References to SciGraph publications

  • 2010-04. Magnetic properties of Bi(Fe1 − xMx)O3 (M = Mn, Ti) in INORGANIC MATERIALS
  • 2007-06. Charge order and spin order in Nd0.5Sr0.5Mn1−x(Gax, Tix)O3 system in SCIENTIA SINICA PHYSICA MECHANICA & ASTRONOMICA
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1134/s002247661808036x

    DOI

    http://dx.doi.org/10.1134/s002247661808036x

    DIMENSIONS

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