Crystal Structure and Luminescence of a Novel Binuclear Zinc(II) Complex with Di-2-Pyridylamine And 4,4′-Sulfonyldibenzoate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

C. Yuan, S. N. Liu, X. J. Xu

ABSTRACT

A binuclear Zn(II) complex [Zn2(SDBA)2(DPA)2.2H2O] (1) (DPA = di-2-pyridylamine, H2SDBA = 4,4′- sulfonyldibenzoic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is a binuclear zinc(II) complex. The binuclear molecules are further connected by three types of N–H...O, C–H...O, and O–H...O hydrogen bonds, generating a three-dimensional supramolecular structure. Meanwhile, S–O...π interactions further consolidate the three-dimensional supramolecular framework of 1. In addition, the thermal stability and luminescent properties of the title complex are briefly investigated. The luminescence measurements reveal that complex 1 exhibits fluorescent emission in the solid state at room temperature. More... »

PAGES

1922-1927

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s002247661808022x

DOI

http://dx.doi.org/10.1134/s002247661808022x

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