Synthesis, Molecular and Crystal Structure of Ethyl-4,6(R,S)-Diphenyl-2-Dicyanomethylenecyclohex-3-Ene-1(R,S)-Carboxylate View Full Text


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Article Info

DATE

2018-12

AUTHORS

A. I. Ismiev, K. A. Potekhin, A. V. Maleev, R. K. Askerov, A. M. Maharramov

ABSTRACT

We report a novel three-component condensation of benzalacetophenone, ethyl acetoacetate, and malonodinitrile in a 1:1:1 molar ratio respectively, involving an equimolar amount of morpholine acetate to form ethyl-4,6(R,S)-diphenyl-2-dicyanomethylenecyclohex-3-ene-1(R,S)-carboxylate whose crystal structure is determined by single crystal XRD. The intermolecular interaction is analyzed using an atomatom potential model, and infinite chains of energetically tightly coupled molecules in the crystal structure are identified and described. A weak hydrogen bond of the CAr–H…O type is found. More... »

PAGES

1911-1917

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476618080206

DOI

http://dx.doi.org/10.1134/s0022476618080206

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111224354


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