[NiEn3]WO4. Crystal Structural Features Of The Phase Transition At 269 K View Full Text


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Article Info

DATE

2018-12

AUTHORS

S. P. Khranenko, A. S. Sukhikh, D. P. Pishchur, P. S. Buneeva, V. Yu. Komarov, S. A. Gromilov

ABSTRACT

The synthesis method for [NiEn3]WO4 complex salt is described. Data of single crystal X-ray diffraction at 115 K are: space group p3¯, a = 15.9633(5) Å, c = 9.9446(4) Å, V = 2194.6(1) Å3, Z = 6, dx = 2.210 g/cm3, Ni–N is 2.120(2)-2.149(2) Å, ∠N–Ni–N is 80.69(7)-82.28(7)°. From the differential scanning calorimetry data it is found that a phase transition occurs at 269 K. The crystal structural characteristics at 298 K are as follows: space group p3¯1c, a = 9.2641(3) Å, c = 9.9817(3) Å, V = 741.89(4) Å3, Z = 2, dx = 2.179 g/cm3, Ni–N is 2.128(2) Å, ∠N–Ni–N is 81.05(12)°. The phase transition is shown to correspond to the disordering of tungstate anions over three positions. The comparative analysis of N–H…O and C–H…O interionic contacts is performed. More... »

PAGES

1897-1902

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http://scigraph.springernature.com/pub.10.1134/s0022476618080188

DOI

http://dx.doi.org/10.1134/s0022476618080188

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https://app.dimensions.ai/details/publication/pub.1111224352


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