Structure-Forming Role of Heavy Cations in Sr3B2SiO8 (Sr(B,Si)O2.67) and Ba3B6Si2O16 Borosilicates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

S. V. Borisov, N. V. Pervukhina, S. A. Magarill

ABSTRACT

The crystallographic analysis of the orthorhombic (Pnma) structure of Sr3B2SiO8 ≈ (Sr(B,Si)O2.67) shows that its experimentally found symmetry is determined by the geometry of the Sr sublattice where the anion radical without this symmetry simulates it by the statistical averaging of four variants of real configurations. With a reduced fraction of heavy atoms in the triclinic (Р1) structure of Ba3B6Si2O16, the Ba and Si cations whose sublattice determines the presence of additional pseudosymmetry form the skeleton of the structure. More... »

PAGES

1648-1652

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s002247661807017x

DOI

http://dx.doi.org/10.1134/s002247661807017x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110647482


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