Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3] View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-03

AUTHORS

A. M. Cheplakova, I. S. Fedoseev, P. V. Dorovatovskii, V. A. Lazarenko, Ya. V. Zubavichus, V. N. Khrustalev, V. P. Fedin

ABSTRACT

The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by π–π interactions between the phenyl rings. More... »

PAGES

494-496

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476618020348

DOI

http://dx.doi.org/10.1134/s0022476618020348

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1104406487


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