Structure and Luminescent Properties of Cluster Complexes with the {Mo6(μ3-SeCl7)}3+ Core View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-01

AUTHORS

M. A. Mikhailov, A. V. Virovets, E. V. Peresypkina, K. A. Brylev, M. N. Sokolov

ABSTRACT

The selenium atom substitution for one of the capping chloride ligands in [Mo6(μ3-Cl8)Cl6]2– under the action of H2Se in situ results in a [Mo6(μ3-SeCl7)Cl6]3– cluster which is isolated and structurally characterized in the form of (Bu4N)3[Mo6(μ3-SeCl7)Cl6] (I). In the acetonitrile solution the complex exhibits luminescence (λmax = 775 nm, τem = 1.8 μs, Φem = 0.004). When the solution of I in acetonitrile is heated, a partial solvolysis product of the composition (Bu4N)2[Mo6(μ3-SeCl7)Cl5(CH3CN)] (II) is isolated and structurally characterized. More... »

PAGES

177-181

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476618010274

DOI

http://dx.doi.org/10.1134/s0022476618010274

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101552148


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