X-ray emission study of the electronic structure of binuclear niobium complexes with (S2)2–disulfide bridging ligands View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-12

AUTHORS

L. N. Mazalov, A. D. Fedorenko, G. K. Parygina, A. L. Gushchin, M. N. Sokolov, S. A. Dalmatova

ABSTRACT

The electronic structure of binuclear niobium complexes [Nb2S4(acac)4] and K4[Nb2S4(ox)4] is studied by X-ray emission fluorescent spectroscopy and quantum chemistry techniques. Data on the partial atomic composition of highest occupied molecular orbitals of the complexes are obtained. The energy positions of bonding and antibonding frontier molecular orbitals observed in the X-ray emission spectra of binuclear [Nb2((S2)2–)2]4+ clusters are determined by the analysis of overlap populations. More... »

PAGES

1625-1632

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476617080200

DOI

http://dx.doi.org/10.1134/s0022476617080200

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1100740261


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