X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-11

AUTHORS

A. D. Fedorenko, L. N. Mazalov, E. Yu. Fursova, V. I. Ovcharenko, A. V. Kalinkin, S. A. Lavrukhina

ABSTRACT

The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core. More... »

PAGES

1166-1172

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URI

http://scigraph.springernature.com/pub.10.1134/s0022476617060142

DOI

http://dx.doi.org/10.1134/s0022476617060142

DIMENSIONS

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