Structure and thermal properties of a novel volatile bis(1,1,1-trifluoro-5,5-dimethyl-3-hexene-4-imino-2-onate) platinum(II) compound View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-09

AUTHORS

G. I. Zharkova, I. A. Baidina, A. I. Smolentsev, P. A. Stabnikov, N. B. Morozova

ABSTRACT

A novel volatile Pt(II)β-iminoketonate complex is synthesized. β-Aminovinylketone H(i-ptac) = [CF3–C(O)–CH=C(NH2)–C(CH3)3] is used as a ligand. The XRD method is used to determine the structures of the ligand and the complex. The crystallographic data for C16H22F6N2O2Pt are as follows: a = 10.0716(4) Å, b = 10.9572(4) Å, c = 9.6322(4) Å, β = 110.9010(10)°, space group С2/m, Z = 2, R = 0.011. The platinum atom has a square planar coordination with two oxygen and two nitrogen atoms of two bidentately linked ketoiminate ligands in trans-position; the PtO2N2 coordination site is formed. More... »

PAGES

970-974

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s002247661705016x

DOI

http://dx.doi.org/10.1134/s002247661705016x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1092332141


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