Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine View Full Text


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Article Info

DATE

2017-09

AUTHORS

O. G. Shakirova, L. G. Lavrenova, N. V. Kuratieva, A. S. Bogomyakov, L. A. Sheludyakova, A. P. Mosalkova, Yu. V. Grigoriev

ABSTRACT

Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K. More... »

PAGES

919-925

References to SciGraph publications

  • 2004. Structural Aspects of Spin Crossover. Example of the [FeIILn(NCS)2] Complexes in SPIN CROSSOVER IN TRANSITION METAL COMPOUNDS II
  • 2004. Special Classes of Iron(II) Azole Spin Crossover Compounds in SPIN CROSSOVER IN TRANSITION METAL COMPOUNDS I
  • 2004. Structural Investigations of Tetrazole Complexes of Iron(II) in SPIN CROSSOVER IN TRANSITION METAL COMPOUNDS II
  • 1986. Magnetochemistry in NONE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s0022476617050092

    DOI

    http://dx.doi.org/10.1134/s0022476617050092

    DIMENSIONS

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