Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion View Full Text


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Article Info

DATE

2017-07

AUTHORS

T. I. Lappi, Ya. M. Gayfulin, A. I. Smolentsev, Yu. V. Mironov

ABSTRACT

The [Zn(H2O)4]3[Re12CS14(μ-SO2)(μ-S)2(CN)6]0.875[Re12CS14(μ-S)3(CN)6]0.125•6H2O compound (1) containing a new [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– cluster anion is synthesized by the reaction of ZnCl2 and K6[Re12CS14(μ-S/SO/SO2)3(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) Å, b = 28.2551(9) Å, c = 9.7775(3) Å, V = 6100.9(3) Å3, Z = 4, dcalc = 3.806 g/cm3. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H2O)4]2+ cations, and solvate H2O molecules linked by hydrogen bonds. More... »

PAGES

835-837

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URI

http://scigraph.springernature.com/pub.10.1134/s002247661704031x

DOI

http://dx.doi.org/10.1134/s002247661704031x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1091784014


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