Crystal structure of (1,1,1-trifluoro-5,5-dimethylhexan-2,4-dionato)silver(I) View Full Text


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Article Info

DATE

2016-12

AUTHORS

I. S. Fedoseev, E. S. Vikulova, I. Yu. Il’in, A. I. Smolentsev, M. R. Gallyamov, N. B. Morozova

ABSTRACT

A novel complex [Ag(ptac)]∞ (1) (ptac = tBuC(O)CHC(O)CF3) has been prepared by interaction of Ag2O and Hptac, its structure being elucidated by single crystal X-ray diffraction. The complex has a chain polymeric structure originating from tetradentate-μ-bridging coordination of the ptac ligands and interactions Ag–Cγ between adjacent {Ag(ptac)} fragments. The coordination environment of the silver atom is a distorted square pyramid. The distances Ag–O are 2.362(10)-2.600(10) Å; Ag–Cγ–2.32(2) Å and 2.328(13) Å; Ag···Ag–3.3497(13) Å and 3.3750(13) Å; the values of chelate angles OAgO fall within 64.6(4)-71.1(3)°. Under thermogravimetric experiment conditions compound 1 decomposes within temperature range 100-385°С with formation of silver metal. More... »

PAGES

1667-1670

References to SciGraph publications

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http://scigraph.springernature.com/pub.10.1134/s0022476616080242

DOI

http://dx.doi.org/10.1134/s0022476616080242

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135 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
136 Novosibirsk National Research State University, Novosibirsk, Russia
137 rdf:type schema:Organization
 




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