Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2– View Full Text


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Article Info

DATE

2016-12

AUTHORS

A. I. Gubanov, A. M. Danilenko, A. I. Smolentsev, N. V. Kuratieva, A. B. Venediktov, S. V. Korenev

ABSTRACT

Double complex salts (DCS) α-[Pd(NH3)4][IrF6]·H2O (P21/m, a = 6.3181(3) Å, b = 10.8718(5) Å, с = 7.4526(4) Å, β = 103.568(2)°), β-[Pd(NH3)4][IrF6]·H2O (P21/с, a = 8.5773(3) Å, b = 10.8791(4) Å, с = = 12.6741(3) Å, β = 122.497(2)°), [Pd(NH3)4]3[IrF6]2Cl2·H2O (P-1, a = 7.6080(2) Å, b = 7.6274(2) Å, с = 11.8070(3) Å, β = 122.497(2)°), and [Pd(NH3)4]2[IrF6]NO3 (Fm-3m, a = 11.21210(10) Å) have been synthesized and structurally characterized for the first time. The existence of polymorphs for the DCS has been revealed. The influence of the chemical composition of the initial reagents on the reaction course and, respectively, the products, has been demonstrated. A hypothesis on the influence of the second coordination sphere on the formation of one or the other polymorph of the DCS has been suggested. It has been shown that the series α-[Pd(NH3)4][МF6]·H2O (M = Pt, Pd) exhibits isostructurality. More... »

PAGES

1606-1612

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476616080175

DOI

http://dx.doi.org/10.1134/s0022476616080175

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1053792370


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