Structure of platinum coatings obtained by chemical vapor deposition View Full Text


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Article Info

DATE

2015-11

AUTHORS

N. V. Gelfond, V. V. Krisyk, S. I. Dorovskikh, D. B. Kal’nyi, E. A. Maksimovskii, Yu. V. Shubin, S. V. Trubin, N. B. Morozova

ABSTRACT

To the best of our knowledge, it is the first time that the method of chemical vapor deposition (MOCVD) with platinum(II) bis(acetylacetonate) (Pt(acac)2) is used to obtain platinum coatings on the cathodes and anodes of the electrodes for pacemakers. The deposition processes are carried out under reduced pressure in the presence of oxygen. The phase and elemental composition, structure, and morphology of the coatings are examined by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). Platinum coatings with a columnar structure are prepared in the temperature range 280-340°C. An increase in the deposition temperature leads to a change in the structure of the coatings and reduction in their thickness. Cyclic voltammetry (CV) is used to estimate the specific capacities of the platinum coatings on the cathodes and anodes, the maximum values of which are 426 mC/cm2 and 1160 mC/cm2, respectively. More... »

PAGES

1215-1219

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476615060347

DOI

http://dx.doi.org/10.1134/s0022476615060347

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