Crystal structure and thermal properties of (1,1,1,5,5,5-hexafluoropentanoato-4)··(dicarbonyl)iridium(I) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-11

AUTHORS

E. S. Vikulova, I. Yu. Ilyin, K. I. Karakovskaya, D. A. Piryazev, N. B. Morozova

ABSTRACT

The Ir(CO)2(hfac) complex (hfac = CF3C(O)CHC(O)CF3) has been studied by X-ray crystallographic analysis. The crystallographic data are as follows: space group Cmc21, a = 8.680(4) Å, b = 18.951(1) Å, c = 6.491(3) Å, V = 1067.7(8) Å3, Z = 4, R = 0.0327. The structure is molecular; the coordination polyhedron of iridium adopts a distorted square geometry. The average Ir–O and Ir–C distances are 2.06(1) Å and 1.82(4) Å respectively. The OIrO and CIrC angles are nearly equal (88.7(5)° and 89(1)° respectively). The thermal properties of the complex have been studied by thermogravimetry. More... »

PAGES

1212-1214

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476615060335

DOI

http://dx.doi.org/10.1134/s0022476615060335

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033929957


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