Structure of the framework complex K0.4Cs0.6{Cd(H2O)2Re6S8(CN)4(OH)(H2O)}•8H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-09

AUTHORS

A. Yu. Ledneva, A. V. Virovets, N. G. Naumov

ABSTRACT

By single crystal X-ray diffraction, the structure of a new compound based on octahedral mixed-ligand anionic cluster complexes of rhenium and cadmium(II) cations is determined: K0.4Cs0.6{Cd(H2O)2Re6S8(CN)4(OH)(H2O)}•8H2O (1). The compound has a framework structure with a pts (platinum sulfide) topology. The cluster anions are additionally chained together by strong OH⋯H2O hydrogen bonds between the terminal ligands of neighboring clusters; the O⋯O distance is 2.464 Å. More... »

PAGES

1024-1027

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476615050327

DOI

http://dx.doi.org/10.1134/s0022476615050327

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014088597


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