Local atomic structure of copper complexes with 2-tosylaminobenzylidene-2′-amino-5′-chlorothiophenol View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-06

AUTHORS

A. S. Burlov, V. G. Vlasenko, S. A. Mashchenko, D. A. Garnovskii, A. I. Uraev, S. I. Levchenkov, Ya. V. Zubavichus, T. V. Lifintseva

ABSTRACT

A new 2-tosylaminobenzylidene-2′-amino-5′-chlorothiophenol ligand and its mono- and binuclear copper complexes are synthesized. Their structures are characterized by IR, 1H NMR, and magnetochemistry. In the copper binuclear complex there is the antiferromagnetic exchange interaction between paramagnetic centers. The dimeric structure of the copper complex is confirmed by X-ray absorption spectroscopy. The addition of pyridine to the dimeric cooper complex results in the formation of a paramagnetic monomeric structure in which pyridine is coordinated to metal via the nitrogen atom. More... »

PAGES

504-510

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476615030178

DOI

http://dx.doi.org/10.1134/s0022476615030178

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005949298


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