Structural modifications of VO2+ chelates in the organic matter of oils and bitumens from the EPR spectra View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-06

AUTHORS

L. G. Gilinskaya, L. S. Borisova, E. A. Kostyreva

ABSTRACT

Vanadyl metal-organic complexes (VO2+) in genetically different fractions of natural oils and bitumens are studied using EPR. Phenolic vanadyl complexes are identified having an isotropic spectrum with the parameters Ao = 8.82 mT, go = 1.996, as opposed to the previously studied axially symmetric spectra of vanadyl porphyrin complexes with Ao = 9.46 mT, go = 1.976 (A‖ = 16.79 mT, A⊥ = 5.78 mT, g‖ = 1.964, g⊥ = 1.983). The simultaneous presence of both types of vanadyl complexes in the samples under consideration results in a complex spectrum, which is identified by computer simulation using the ESR1 software. More... »

PAGES

436-445

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476615030051

DOI

http://dx.doi.org/10.1134/s0022476615030051

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007138405


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.465281.c", 
          "name": [
            "Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gilinskaya", 
        "givenName": "L. G.", 
        "id": "sg:person.07416050056.87", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07416050056.87"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Trofimuk Institute of Petroleum-Gas Geology and Geophysics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Trofimuk Institute of Petroleum-Gas Geology and Geophysics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Borisova", 
        "givenName": "L. S.", 
        "id": "sg:person.011526666721.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011526666721.23"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Trofimuk Institute of Petroleum-Gas Geology and Geophysics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Trofimuk Institute of Petroleum-Gas Geology and Geophysics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kostyreva", 
        "givenName": "E. A.", 
        "id": "sg:person.010015760732.57", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010015760732.57"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf00751901", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049007155", 
          "https://doi.org/10.1007/bf00751901"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10947-008-0120-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025223062", 
          "https://doi.org/10.1007/s10947-008-0120-6"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-06", 
    "datePublishedReg": "2015-06-01", 
    "description": "Vanadyl metal-organic complexes (VO2+) in genetically different fractions of natural oils and bitumens are studied using EPR. Phenolic vanadyl complexes are identified having an isotropic spectrum with the parameters Ao = 8.82 mT, go = 1.996, as opposed to the previously studied axially symmetric spectra of vanadyl porphyrin complexes with Ao = 9.46 mT, go = 1.976 (A\u2016 = 16.79 mT, A\u22a5 = 5.78 mT, g\u2016 = 1.964, g\u22a5 = 1.983). The simultaneous presence of both types of vanadyl complexes in the samples under consideration results in a complex spectrum, which is identified by computer simulation using the ESR1 software.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0022476615030051", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "1573-8779"
        ], 
        "name": "Journal of Structural Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "keywords": [
      "vanadyl complexes", 
      "metal-organic complexes", 
      "vanadyl porphyrin complexes", 
      "porphyrin complexes", 
      "EPR spectra", 
      "natural oils", 
      "structural modifications", 
      "complexes", 
      "isotropic spectrum", 
      "parameter ao", 
      "spectra", 
      "organic matter", 
      "different fractions", 
      "bitumens", 
      "complex spectra", 
      "chelates", 
      "EPR", 
      "oil", 
      "symmetric spectrum", 
      "simultaneous presence", 
      "modification", 
      "AO", 
      "computer simulations", 
      "VO2", 
      "presence", 
      "samples", 
      "fraction", 
      "consideration results", 
      "matter", 
      "simulations", 
      "types", 
      "results", 
      "software"
    ], 
    "name": "Structural modifications of VO2+ chelates in the organic matter of oils and bitumens from the EPR spectra", 
    "pagination": "436-445", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1007138405"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0022476615030051"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0022476615030051", 
      "https://app.dimensions.ai/details/publication/pub.1007138405"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-11-24T20:59", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_645.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0022476615030051"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0022476615030051'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0022476615030051'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0022476615030051'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0022476615030051'


 

This table displays all metadata directly associated to this object as RDF triples.

115 TRIPLES      21 PREDICATES      60 URIs      50 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0022476615030051 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author Nf92518655fee4c17b66cbc3cac8948c7
4 schema:citation sg:pub.10.1007/bf00751901
5 sg:pub.10.1007/s10947-008-0120-6
6 schema:datePublished 2015-06
7 schema:datePublishedReg 2015-06-01
8 schema:description Vanadyl metal-organic complexes (VO2+) in genetically different fractions of natural oils and bitumens are studied using EPR. Phenolic vanadyl complexes are identified having an isotropic spectrum with the parameters Ao = 8.82 mT, go = 1.996, as opposed to the previously studied axially symmetric spectra of vanadyl porphyrin complexes with Ao = 9.46 mT, go = 1.976 (A‖ = 16.79 mT, A⊥ = 5.78 mT, g‖ = 1.964, g⊥ = 1.983). The simultaneous presence of both types of vanadyl complexes in the samples under consideration results in a complex spectrum, which is identified by computer simulation using the ESR1 software.
9 schema:genre article
10 schema:isAccessibleForFree false
11 schema:isPartOf N33c5280db74b42dfabe274083b641d0f
12 Nc0f72c5735ec439b8150d5e2e18345e7
13 sg:journal.1135923
14 schema:keywords AO
15 EPR
16 EPR spectra
17 VO2
18 bitumens
19 chelates
20 complex spectra
21 complexes
22 computer simulations
23 consideration results
24 different fractions
25 fraction
26 isotropic spectrum
27 matter
28 metal-organic complexes
29 modification
30 natural oils
31 oil
32 organic matter
33 parameter ao
34 porphyrin complexes
35 presence
36 results
37 samples
38 simulations
39 simultaneous presence
40 software
41 spectra
42 structural modifications
43 symmetric spectrum
44 types
45 vanadyl complexes
46 vanadyl porphyrin complexes
47 schema:name Structural modifications of VO2+ chelates in the organic matter of oils and bitumens from the EPR spectra
48 schema:pagination 436-445
49 schema:productId N341d0c7b406243a49a5303e5fe255718
50 N7fa0a419d1c34cb2843b1d8c0b84a4ee
51 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007138405
52 https://doi.org/10.1134/s0022476615030051
53 schema:sdDatePublished 2022-11-24T20:59
54 schema:sdLicense https://scigraph.springernature.com/explorer/license/
55 schema:sdPublisher Nb508e044daaf47aa956e4890bb0acfd5
56 schema:url https://doi.org/10.1134/s0022476615030051
57 sgo:license sg:explorer/license/
58 sgo:sdDataset articles
59 rdf:type schema:ScholarlyArticle
60 N0b07bc63d47f455c8d3ad79ddecf2c07 rdf:first sg:person.011526666721.23
61 rdf:rest Na7591e5a102f4623b01717d6062290db
62 N33c5280db74b42dfabe274083b641d0f schema:volumeNumber 56
63 rdf:type schema:PublicationVolume
64 N341d0c7b406243a49a5303e5fe255718 schema:name dimensions_id
65 schema:value pub.1007138405
66 rdf:type schema:PropertyValue
67 N7fa0a419d1c34cb2843b1d8c0b84a4ee schema:name doi
68 schema:value 10.1134/s0022476615030051
69 rdf:type schema:PropertyValue
70 Na7591e5a102f4623b01717d6062290db rdf:first sg:person.010015760732.57
71 rdf:rest rdf:nil
72 Nb508e044daaf47aa956e4890bb0acfd5 schema:name Springer Nature - SN SciGraph project
73 rdf:type schema:Organization
74 Nc0f72c5735ec439b8150d5e2e18345e7 schema:issueNumber 3
75 rdf:type schema:PublicationIssue
76 Nf92518655fee4c17b66cbc3cac8948c7 rdf:first sg:person.07416050056.87
77 rdf:rest N0b07bc63d47f455c8d3ad79ddecf2c07
78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
79 schema:name Chemical Sciences
80 rdf:type schema:DefinedTerm
81 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
82 schema:name Inorganic Chemistry
83 rdf:type schema:DefinedTerm
84 sg:journal.1135923 schema:issn 0022-4766
85 1573-8779
86 schema:name Journal of Structural Chemistry
87 schema:publisher Pleiades Publishing
88 rdf:type schema:Periodical
89 sg:person.010015760732.57 schema:affiliation grid-institutes:grid.415877.8
90 schema:familyName Kostyreva
91 schema:givenName E. A.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010015760732.57
93 rdf:type schema:Person
94 sg:person.011526666721.23 schema:affiliation grid-institutes:grid.415877.8
95 schema:familyName Borisova
96 schema:givenName L. S.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011526666721.23
98 rdf:type schema:Person
99 sg:person.07416050056.87 schema:affiliation grid-institutes:grid.465281.c
100 schema:familyName Gilinskaya
101 schema:givenName L. G.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07416050056.87
103 rdf:type schema:Person
104 sg:pub.10.1007/bf00751901 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049007155
105 https://doi.org/10.1007/bf00751901
106 rdf:type schema:CreativeWork
107 sg:pub.10.1007/s10947-008-0120-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025223062
108 https://doi.org/10.1007/s10947-008-0120-6
109 rdf:type schema:CreativeWork
110 grid-institutes:grid.415877.8 schema:alternateName Trofimuk Institute of Petroleum-Gas Geology and Geophysics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
111 schema:name Trofimuk Institute of Petroleum-Gas Geology and Geophysics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
112 rdf:type schema:Organization
113 grid-institutes:grid.465281.c schema:alternateName Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
114 schema:name Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
115 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...