Two-dimensional coordination polymers based on pyridine-containing cations of cu(II) and Ni(II) and 1,3,5-benzenetricarboxylate anion and their supramolecular structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-12

AUTHORS

L. V. Tsymbal, I. L. Andriichuk, Ya. D. Lampeka, V. B. Arion

ABSTRACT

New coordination compounds based on 1,3,5-benzenetricarboxylate (btc3−) and complex cations of copper(II) and nickel(II) with monodentate ligands {{[Cu(py)3]3(btc)2}·4,5H2O}n (1) and {[Ni(py)3(H2O)]3(btc)2}n (2) were obtained. The molecular and crystal structures of these compounds and their isomorphism were determined by X-ray diffraction analysis. Crystals of 1 and 2 are characterized by a layered structure due to the stacking of two-dimensional coordination-polymer layers interacting with each other through C-H…π non-covalent interactions and C-H…O weak hydrogen bonds. It is shown that these compounds are potentially highly porous materials with coordinatively unsaturated metal ions (Lewis acid sites). More... »

PAGES

1466-1473

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476614080137

DOI

http://dx.doi.org/10.1134/s0022476614080137

DIMENSIONS

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139 https://www.grid.ac/institutes/grid.418751.e schema:alternateName National Academy of Sciences of Ukraine
140 schema:name Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
141 rdf:type schema:Organization
 




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