Crystal structures of [Ln5(dbm)10(OH)5]·nCH2Cl2 (Ln = Yb, n = 2, Ln = Er, n = 6) View Full Text


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Article Info

DATE

2014-12

AUTHORS

T. S. Sukhikh, D. A. Bashirov, N. V. Kuratieva, A. I. Smolentsev, S. N. Konchenko

ABSTRACT

The structures of [Yb5(dbm)10(OH)5]·2CH2Cl2 and [Er5(dbm)10(OH)5]·6CH2Cl2 (dbm = dibenzoylmethanate) were established. The compounds are crystallized in different space groups P4/n and P21/n correspondingly. Ytterbium complex is isostructural to known [Ln5(dbm)10(OH)5]·2C7H8 (Ln = Er, Yb). Structural type of erbium complex prepared in this work has no analogues amongst similar pentanuclear dibenzoylmethanate complexes. The cavities types of the structures filled by CH2Cl2 molecules are different. More... »

PAGES

1437-1441

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476614080095

DOI

http://dx.doi.org/10.1134/s0022476614080095

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032400072


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