Crystal structure of the octahedral cluster complex trans-[{Re6S8}(pyz)4I2]·2pyz View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-01

AUTHORS

M. A. Shestopalov, A. A. Ivanov, A. I. Smolentsev, Yu. V. Mironov

ABSTRACT

The cluster complex of the composition trans-[{Re6S8}(pyz)4I2]· 2pyz (pyz is pyrazine) is obtained by the reaction of Cs4[{Re6S8}I6] with molten pyrazine. The compound crystallizes in the triclinic space group with the following unit cell parameters: a = 9.0562(7) Å, b = 10.2502(7) Å, c = 12.6783(9) Å, α = 98.537(3)°, β = 107.573(2)°, γ = 106.943(3)°, V = 1036.6(1) Å3, Z = 1, dcalc = 3.377 g/cm3. The crystal structure is built of trans-[{Re6S8}(pyz)4I2] cluster complexes and uncoordinated pyrazine molecules. More... »

PAGES

139-141

References to SciGraph publications

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URI

http://scigraph.springernature.com/pub.10.1134/s0022476614010235

DOI

http://dx.doi.org/10.1134/s0022476614010235

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https://app.dimensions.ai/details/publication/pub.1049244534


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