Properties and structure of new volatile phenyl-containing β-diketonates of trimethylplatinum(IV): (CH3)3Pt(btfa)H2O, (CH3)3Pt(bac)Py, and initial complex [(CH3)3PtI]4 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-11

AUTHORS

G. I. Zharkova, I. A. Baidina, A. I. Smolentsev, I. K. Igumenov

ABSTRACT

By interaction of trimethylplatinum(IV) iodide with phenyl-containing β-diketonates, the volatile monomeric complexes of trimethylplatinum(IV) based on benzoyltrifluoroacetone (Hbtfa) and benzoylacetone (Hbac) of the composition (CH3)3Pt(btfa)H2O (I) and (CH3)3Pt(bac)Py (II) are obtained. Synthesis of the complexes is described; data of elemental analysis and IR spectra are reported; thermal characteristics are studied by thermogravimetry. For the first time, a single crystal X-ray diffraction study of complexes (I), (II), and the initial tetrameric complex [(CH3)3PtI]4 (III) is performed. More... »

PAGES

1083-1090

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476613060127

DOI

http://dx.doi.org/10.1134/s0022476613060127

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024883021


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