Interpretation of X-ray photoelectron spectra of free nitroxyl radicals View Full Text


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Article Info

DATE

2013-09

AUTHORS

L. N. Mazalov, A. D. Fedorenko, V. I. Ovcharenko, E. V. Tret’yakov, E. Yu. Fursova, N. A. Kryuchkova, A. V. Kalinkin, E. V. Trushin

ABSTRACT

N1s and O1s X-ray photoelectron spectra of stable nitroxyl radicals (substituted piperidine-1-oxyl, 2-imidazoline-1-oxyl, and 2-imidazoline-3-oxide-1-oxyl) and also diamagnetic derivatives with a {ONCNO} fragment are measured. It is shown that the structure of N1s and O1s X-ray photoelectron spectra of nitroxyls is determined by charge transfer processes between different parts of the molecule to screen the X-ray hole and the spin-spin interaction of unpaired electrons on the HOMO and 1s level. More... »

PAGES

898-906

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476613050090

DOI

http://dx.doi.org/10.1134/s0022476613050090

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038476884


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