Structural characterization of dicyanidobis-(N,N′-dimethylthiourea-κS)cadmium(II) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-07

AUTHORS

M. R. Malik, T. Rüffer, H. Lang, A. A. Isab, S. Ali, S. Ahmad, H. Stoeckli-Evans

ABSTRACT

A cadmium(II) complex dicyanidobis(N,N′-dimethylthiourea-S) cadmium(II) [Cd(Dmtu)2(CN)2] (1) is prepared and its structure in the solid state is determined by single crystal X-ray structural analysis. The cadmium(II) ion is four-coordinate having a distorted tetrahedral geometry composed of two cyanide C atoms and two thione S atoms of N,N′-dimethylthiourea (dmtu). The molecular structure is stabilized by intermolecular N-H…N(CN) hydrogen bonding interactions that lead to a 3D network structure. The complex was also characterized by IR and NMR spectroscopy. More... »

PAGES

810-814

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476613040240

DOI

http://dx.doi.org/10.1134/s0022476613040240

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021548465


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