Binuclear cluster complexes of molybdenum containing 2,2′-bipyridine and 1,10-phenanthroline: Synthesis and structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-07

AUTHORS

A. L. Gushchin, Yu. L. Laricheva, N. I. Alferova, A. V. Virovets, M. N. Sokolov

ABSTRACT

By the interaction between (Et4N)2[Mo2O2S8] and I2 in DMF with a subsequent addition of 2,2′-bipyridine or 1,10-phenanthroline, new binuclear complexes [Mo2O2S2I2(bipy)2] (1) and [Mo2O2S2I2(phen)2] (2) are obtained. The structure of [Mo2O2S2I2(bipy)2] is determined using single crystal X-ray diffraction. The compounds are characterized by elemental analysis and IR spectra. The [MoO(S2)2(bipy)] complex as a product of oxidative destruction of 1 is isolated and characterized. More... »

PAGES

752-758

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476613040148

DOI

http://dx.doi.org/10.1134/s0022476613040148

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044756678


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