Magnetic properties of new complexes of 3d metal chlorides with 3-amino-4-ethoxycarbonylpyrazole View Full Text


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Article Info

DATE

2013-07

AUTHORS

L. G. Lavrenova, A. S. Zhilin, A. S. Bogomyakov, L. A. Sheludyakova, A. V. Alekseev, S. F. Vasilevskii

ABSTRACT

New complexes of Co(II), Ni(II), and Cu(II) chlorides with 3-amino-4-ethoxycarbonylpyrazole (L) of the composition ML2Cl2 are synthesized. The compounds are studied by powder X-ray diffraction, electronic and IR spectroscopy, static magnetic susceptibility (temperature range 2–300 K). It is found that in the ML2Cl2 complexes (M = Co(II), Ni(II), Cu(II)) ferromagnetic exchange interactions between the unpaired electrons of metal ions occur. In [CoL2Cl2] and [NiL2Cl2] compounds a transition to the magnetically ordered state (Tc ≊ 10–12 K) is observed. More... »

PAGES

713-718

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476613040082

DOI

http://dx.doi.org/10.1134/s0022476613040082

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049053845


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