Crystal structure of [Pt3S2(P(CH2OH)3)6](PF6)(OH)·H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-05

AUTHORS

A. V. Anyushin, M. N. Sokolov, A. V. Virovets, V. P. Fedin

ABSTRACT

[Pt3S2(P(CH2OH)3)6](PF6)(OH)·H2O (1) is obtained by a reaction of [Pt3S2(P(CH2OH)3)6]Cl2 with NH4PF6. The crystal structure of 1 was determined by a single crystal X-ray diffraction analysis (space group R{ie638-1}c, a = 12.0042(2) Å, c = 52.6879(11) Å, V = 6575.2(2), Z = 6, C18H57F6O20P7Pt3S2, dx = 2.385 g/cm3, T = 150 K, R1 = 0.044 for 2123 F0 > 4δ(F) until 2θmax = 63°). The cations contain a {Pt3(μ3-S)2}2+ core with nonbonding Pt…Pt distances of 3.1536(6) Å. The Pt atoms are in a square planar environment; the Pt-S and Pt-P bond lengths are 2.3586(16) Å and 2.260(2) Å respectively. More... »

PAGES

638-641

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s002247661303027x

DOI

http://dx.doi.org/10.1134/s002247661303027x

DIMENSIONS

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