Crystal structure and magnetic properties of a new heterometallic complex of Pd(II)-Cu(II) with 1-aminoethylidene-1,1-diphosphonic acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-03

AUTHORS

A. N. Kozachkova, N. V. Tsaryk, A. V. Dudko, V. I. Pekhnyo, V. M. Novotortsev, I. L. Eremenko, V. V. Minin, N. N. Efimov, E. A. Ugolkova

ABSTRACT

A heterometallic complex of Pd(II)-Cu(II) with 1-aminoethylidene-1,1-diphosphonic (AEDP) acid (C4H22CuN2O16P4Pd)n (I) is synthesized. Single crystals of compound I are obtained; its crystal structure is determined by X-ray crystallography. The crystals are orthorhombic, space group Pbcn, a = 18.366(3) Å, b = 9.7661(17) Å, c = 20.198(4) Å, V = 3622.8(11) Å3, Z = 8, dx = 2.376 g/cm3. The compound crystallizes as a coordination polymer; the square environment of Pd(II) is formed by nitrogen atoms of amino groups and oxygen atoms of phosphonic groups, while at two non-equivalent copper atoms the octahedral environment is formed by oxygen atoms of phosphonic groups and water molecules. The crystal structure of compound I is characterized by the formation of a branched network of hydrogen bonds. Based on the analysis of the temperature dependence of the magnetic susceptibility it is found that for the heterometallic complex of Pd(II)-Cu(II) with AEDP antiferromagnetic interactions between the paramagnetic centers are dominant. More... »

PAGES

315-320

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476613020066

DOI

http://dx.doi.org/10.1134/s0022476613020066

DIMENSIONS

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