Structure of Mn(II), Co(II), Ni(II), and Cu(II) complexes with triformylmethane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-02

AUTHORS

E. V. Tretyakov, S. E. Tolstikov, G. V. Romanenko, A. S. Bogomyakov, R. Z. Sagdeev, V. M. Novotortsev, V. I. Ovcharenko

ABSTRACT

Previously unknown [ML2(H2O)n] bischelates, where M is Mn(II), Co(II), Ni(II), or Cu(II) and L is deprotonated triformylmethane, are studied by X-ray diffraction analysis. It is revealed that in the crystals of all compounds there are multiple hydrogen bonds linking bischelate molecules into polymer layers or a single framework. The character of the temperature dependence of the effective magnetic moment [ML2(H2O)n] indicates the existences of weak intracrystalline exchange interactions between the unpaired electrons of the paramagnetic centers. More... »

PAGES

104-109

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476613010149

DOI

http://dx.doi.org/10.1134/s0022476613010149

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050977176


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