UV spectroscopy of monosubstituted derivatives of 1,2-dihydro-C60-fullerenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-11

AUTHORS

Yu. N. Biglova, V. A. Kraikin, S. A. Torosyan, V. V. Mikheev, S. V. Kolesov, A. G. Mustafin, M. S. Miftakhov

ABSTRACT

UV spectroscopy is used to determine the molar absorption coefficients of C60 fullerene and monosubstituted 1,2-dihydro-C60-fullerenes in different solvents. It is found that the extinction coefficient of C60 at 330 nm (the main absorption band most frequently used for qualitative and quantitative determination of the C60 content) is independent of the nature of the solvent and is ∼54400 M−1·cm−1. The molar absorption coefficients of a series of monosubstituted 1,2-dihydro-C60-fullerenes are practically independent of the chemical structure and the length of the substituent and are 35700 M−1·cm−1 (λ ∼ 328 nm) and 115250 M−1·cm−1 (λ ∼ 257 nm). It is shown that the substitution in fullerene proceeds via the double 6,6 bond, as evidenced by the absorption band at 424 nm in the spectra of these compounds, which is characteristic of monosubstituted methanofullerenes. More... »

PAGES

1081-1086

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476612060091

DOI

http://dx.doi.org/10.1134/s0022476612060091

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046746886


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Chemistry Department, Bashkir State University, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77269.3d", 
          "name": [
            "Chemistry Department, Bashkir State University, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Biglova", 
        "givenName": "Yu. N.", 
        "id": "sg:person.011275460365.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011275460365.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kraikin", 
        "givenName": "V. A.", 
        "id": "sg:person.01116000665.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01116000665.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Torosyan", 
        "givenName": "S. A.", 
        "id": "sg:person.014642167757.85", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014642167757.85"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chemistry Department, Bashkir State University, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77269.3d", 
          "name": [
            "Chemistry Department, Bashkir State University, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mikheev", 
        "givenName": "V. V.", 
        "id": "sg:person.014705737707.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014705737707.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kolesov", 
        "givenName": "S. V.", 
        "id": "sg:person.013075570533.60", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013075570533.60"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chemistry Department, Bashkir State University, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77269.3d", 
          "name": [
            "Chemistry Department, Bashkir State University, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mustafin", 
        "givenName": "A. G.", 
        "id": "sg:person.07676226645.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07676226645.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Miftakhov", 
        "givenName": "M. S.", 
        "id": "sg:person.010702706465.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010702706465.33"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2012-11", 
    "datePublishedReg": "2012-11-01", 
    "description": "UV spectroscopy is used to determine the molar absorption coefficients of C60 fullerene and monosubstituted 1,2-dihydro-C60-fullerenes in different solvents. It is found that the extinction coefficient of C60 at 330 nm (the main absorption band most frequently used for qualitative and quantitative determination of the C60 content) is independent of the nature of the solvent and is \u223c54400 M\u22121\u00b7cm\u22121. The molar absorption coefficients of a series of monosubstituted 1,2-dihydro-C60-fullerenes are practically independent of the chemical structure and the length of the substituent and are 35700 M\u22121\u00b7cm\u22121 (\u03bb \u223c 328 nm) and 115250 M\u22121\u00b7cm\u22121 (\u03bb \u223c 257 nm). It is shown that the substitution in fullerene proceeds via the double 6,6 bond, as evidenced by the absorption band at 424 nm in the spectra of these compounds, which is characteristic of monosubstituted methanofullerenes.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0022476612060091", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "2542-0976"
        ], 
        "name": "Journal of Structural Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "53"
      }
    ], 
    "keywords": [
      "molar absorption coefficient", 
      "UV spectroscopy", 
      "chemical structure", 
      "different solvents", 
      "absorption bands", 
      "C60-fullerene", 
      "C60 fullerene", 
      "absorption coefficient", 
      "solvent", 
      "spectroscopy", 
      "extinction coefficient", 
      "methanofullerene", 
      "fullerenes", 
      "bonds", 
      "substituents", 
      "C60", 
      "compounds", 
      "derivatives", 
      "spectra", 
      "proceeds", 
      "substitution", 
      "structure", 
      "coefficient", 
      "band", 
      "series", 
      "nature", 
      "length", 
      "fullerene proceeds"
    ], 
    "name": "UV spectroscopy of monosubstituted derivatives of 1,2-dihydro-C60-fullerenes", 
    "pagination": "1081-1086", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1046746886"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0022476612060091"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0022476612060091", 
      "https://app.dimensions.ai/details/publication/pub.1046746886"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:28", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_578.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0022476612060091"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0022476612060091'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0022476612060091'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0022476612060091'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0022476612060091'


 

This table displays all metadata directly associated to this object as RDF triples.

131 TRIPLES      21 PREDICATES      54 URIs      46 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0022476612060091 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Na75e743bf02f4f7597b7a37fb6ccff57
4 schema:datePublished 2012-11
5 schema:datePublishedReg 2012-11-01
6 schema:description UV spectroscopy is used to determine the molar absorption coefficients of C60 fullerene and monosubstituted 1,2-dihydro-C60-fullerenes in different solvents. It is found that the extinction coefficient of C60 at 330 nm (the main absorption band most frequently used for qualitative and quantitative determination of the C60 content) is independent of the nature of the solvent and is ∼54400 M−1·cm−1. The molar absorption coefficients of a series of monosubstituted 1,2-dihydro-C60-fullerenes are practically independent of the chemical structure and the length of the substituent and are 35700 M−1·cm−1 (λ ∼ 328 nm) and 115250 M−1·cm−1 (λ ∼ 257 nm). It is shown that the substitution in fullerene proceeds via the double 6,6 bond, as evidenced by the absorption band at 424 nm in the spectra of these compounds, which is characteristic of monosubstituted methanofullerenes.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N017ab536236d4a739db119a17eae6897
11 N32ecb33b531a4393b125f702ee2396b6
12 sg:journal.1135923
13 schema:keywords C60
14 C60 fullerene
15 C60-fullerene
16 UV spectroscopy
17 absorption bands
18 absorption coefficient
19 band
20 bonds
21 chemical structure
22 coefficient
23 compounds
24 derivatives
25 different solvents
26 extinction coefficient
27 fullerene proceeds
28 fullerenes
29 length
30 methanofullerene
31 molar absorption coefficient
32 nature
33 proceeds
34 series
35 solvent
36 spectra
37 spectroscopy
38 structure
39 substituents
40 substitution
41 schema:name UV spectroscopy of monosubstituted derivatives of 1,2-dihydro-C60-fullerenes
42 schema:pagination 1081-1086
43 schema:productId N3f02e8d943fe4d0b9fcc6d9f09710a50
44 Na1ad8ce2b9384512840eaf3d3ec6bfdb
45 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046746886
46 https://doi.org/10.1134/s0022476612060091
47 schema:sdDatePublished 2022-01-01T18:28
48 schema:sdLicense https://scigraph.springernature.com/explorer/license/
49 schema:sdPublisher Nfac8d7b096e345a5a8d16ab881b89e29
50 schema:url https://doi.org/10.1134/s0022476612060091
51 sgo:license sg:explorer/license/
52 sgo:sdDataset articles
53 rdf:type schema:ScholarlyArticle
54 N017ab536236d4a739db119a17eae6897 schema:issueNumber 6
55 rdf:type schema:PublicationIssue
56 N03056860fbe7465fa547a9a634e91f80 rdf:first sg:person.07676226645.49
57 rdf:rest N9c4caa59f1954b60a590d49c57f0fd2c
58 N0334b22117204c38a997489dbc9146ef rdf:first sg:person.013075570533.60
59 rdf:rest N03056860fbe7465fa547a9a634e91f80
60 N24220b7d6a9c4d29a480ddcf2edb31e6 rdf:first sg:person.014705737707.08
61 rdf:rest N0334b22117204c38a997489dbc9146ef
62 N32ecb33b531a4393b125f702ee2396b6 schema:volumeNumber 53
63 rdf:type schema:PublicationVolume
64 N3f02e8d943fe4d0b9fcc6d9f09710a50 schema:name doi
65 schema:value 10.1134/s0022476612060091
66 rdf:type schema:PropertyValue
67 N941c244ba81944208a3fa2f7564a2cbf rdf:first sg:person.014642167757.85
68 rdf:rest N24220b7d6a9c4d29a480ddcf2edb31e6
69 N9c4caa59f1954b60a590d49c57f0fd2c rdf:first sg:person.010702706465.33
70 rdf:rest rdf:nil
71 Na057290a0b17414ab33db0a38ff608ea rdf:first sg:person.01116000665.01
72 rdf:rest N941c244ba81944208a3fa2f7564a2cbf
73 Na1ad8ce2b9384512840eaf3d3ec6bfdb schema:name dimensions_id
74 schema:value pub.1046746886
75 rdf:type schema:PropertyValue
76 Na75e743bf02f4f7597b7a37fb6ccff57 rdf:first sg:person.011275460365.96
77 rdf:rest Na057290a0b17414ab33db0a38ff608ea
78 Nfac8d7b096e345a5a8d16ab881b89e29 schema:name Springer Nature - SN SciGraph project
79 rdf:type schema:Organization
80 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
81 schema:name Chemical Sciences
82 rdf:type schema:DefinedTerm
83 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
84 schema:name Physical Chemistry (incl. Structural)
85 rdf:type schema:DefinedTerm
86 sg:journal.1135923 schema:issn 0022-4766
87 2542-0976
88 schema:name Journal of Structural Chemistry
89 schema:publisher Pleiades Publishing
90 rdf:type schema:Periodical
91 sg:person.010702706465.33 schema:affiliation grid-institutes:grid.4886.2
92 schema:familyName Miftakhov
93 schema:givenName M. S.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010702706465.33
95 rdf:type schema:Person
96 sg:person.01116000665.01 schema:affiliation grid-institutes:grid.4886.2
97 schema:familyName Kraikin
98 schema:givenName V. A.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01116000665.01
100 rdf:type schema:Person
101 sg:person.011275460365.96 schema:affiliation grid-institutes:grid.77269.3d
102 schema:familyName Biglova
103 schema:givenName Yu. N.
104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011275460365.96
105 rdf:type schema:Person
106 sg:person.013075570533.60 schema:affiliation grid-institutes:grid.4886.2
107 schema:familyName Kolesov
108 schema:givenName S. V.
109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013075570533.60
110 rdf:type schema:Person
111 sg:person.014642167757.85 schema:affiliation grid-institutes:grid.4886.2
112 schema:familyName Torosyan
113 schema:givenName S. A.
114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014642167757.85
115 rdf:type schema:Person
116 sg:person.014705737707.08 schema:affiliation grid-institutes:grid.77269.3d
117 schema:familyName Mikheev
118 schema:givenName V. V.
119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014705737707.08
120 rdf:type schema:Person
121 sg:person.07676226645.49 schema:affiliation grid-institutes:grid.77269.3d
122 schema:familyName Mustafin
123 schema:givenName A. G.
124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07676226645.49
125 rdf:type schema:Person
126 grid-institutes:grid.4886.2 schema:alternateName Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia
127 schema:name Institute of Organic Chemistry, Ufa Science Center, Russian Academy of Sciences, Ufa, Russia
128 rdf:type schema:Organization
129 grid-institutes:grid.77269.3d schema:alternateName Chemistry Department, Bashkir State University, Ufa, Russia
130 schema:name Chemistry Department, Bashkir State University, Ufa, Russia
131 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...