XPS spectra of free nitroxyl radicals and their electronic structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-12

AUTHORS

L. N. Mazalov, A. D. Fedorenko, V. I. Ovcharenko, E. V. Tretyakov, E. Yu. Fursova, N. A. Kryuchkova

ABSTRACT

The N(1s) and O(1s) XPS spectra of stable nitroxyl radicals and molecules with a related heterocycle structure: 4,4,5,5-tetramethyl-2-phenyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, 4,4,5,5-tetramethyl-2-(3-nitrophenyl)-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, 4,4,5,5-tetramethyl-2-(2-hydroxyphenyl)-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, 4,4,5,5-tetramethyl-2-(2-hydroxy-3-nitrophenyl)-4,5-dihydro-1Himidazole-3-oxide-1-oxyl, and 4,4,5,5-tetramethyl-2-phenyl-4,5-dihydro-1H-imidazole-3-oxide were studied. The possibility to apply X-ray electron spectra for investigation of the charge electron and spin density distribution on free radical atoms and at their coordination by a metal is considered. More... »

PAGES

102-108

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476611070146

DOI

http://dx.doi.org/10.1134/s0022476611070146

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002378282


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