Unusual crystal and molecular structure of the 1-(1-silatranylmethyl)-3,5-dimethylpyrazole complex with zinc dichloride View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-08

AUTHORS

M. G. Voronkov, É. A. Zel’bst, V. S. Fundamenskii, V. A. Bruskov, A. A. Kashaev, A. S. Soldatenko, Yu. I. Bolgova, O. M. Trofimova

ABSTRACT

The crystal and molecular structure of a 1-(1-silatranylmethyl)-3,5-dimethylpyrazole complex with zinc dichloride (I) is determined by XRD. The coordination polyhedron of the zinc atom is a tetrahedron formed by two covalent Zn-Cl bonds and coordination Zn ← N and Zn ← O bonds. Compound I is the first example of how an endocyclic oxygen atom of the silatranyl fragment participates in the coordination of the metal atom with the formation of a six-membered heterocycle. More... »

PAGES

828

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476611040305

DOI

http://dx.doi.org/10.1134/s0022476611040305

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008012601


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