Crystal structure of [Pd(NH3)4]3[Ir(NO2)6]2·H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-08

AUTHORS

A. A. Rybinskaya, E. A. Shusharina, P. E. Plyusnin, Yu. V. Shubin, S. V. Korenev, S. A. Gromilov

ABSTRACT

A single crystal of [Pd(NH3)4]3[Ir(NO2)6]2·H2O double complex salt is studied by X-ray diffraction. Crystallographic characteristics are as follows: a = 21.0335(5) Å, b = 8.0592(2) Å, c = 21.3452(5) Å, β = 91.254(1)°, V = 3617.43(15) Å3, P21/c space group, Z = 4, dx = 2.714 g/cm3. Single-layer pseudohexagonal packing of complex anions is determined along the [−1 0 1] direction in the structure. Complex cations and crystallization water molecules are located between the mentioned layers. More... »

PAGES

816

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476611040275

DOI

http://dx.doi.org/10.1134/s0022476611040275

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038497827


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rybinskaya", 
        "givenName": "A. A.", 
        "id": "sg:person.014144422711.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014144422711.19"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shusharina", 
        "givenName": "E. A.", 
        "id": "sg:person.010367230757.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010367230757.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia", 
            "Novosibirsk State University, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Plyusnin", 
        "givenName": "P. E.", 
        "id": "sg:person.0643531001.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0643531001.56"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia", 
            "Novosibirsk State University, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shubin", 
        "givenName": "Yu. V.", 
        "id": "sg:person.012641166115.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012641166115.54"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia", 
            "Novosibirsk State University, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korenev", 
        "givenName": "S. V.", 
        "id": "sg:person.0713211235.58", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0713211235.58"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia", 
            "Novosibirsk State University, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gromilov", 
        "givenName": "S. A.", 
        "id": "sg:person.015627070115.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015627070115.78"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2011-08", 
    "datePublishedReg": "2011-08-01", 
    "description": "A single crystal of [Pd(NH3)4]3[Ir(NO2)6]2\u00b7H2O double complex salt is studied by X-ray diffraction. Crystallographic characteristics are as follows: a = 21.0335(5) \u00c5, b = 8.0592(2) \u00c5, c = 21.3452(5) \u00c5, \u03b2 = 91.254(1)\u00b0, V = 3617.43(15) \u00c53, P21/c space group, Z = 4, dx = 2.714 g/cm3. Single-layer pseudohexagonal packing of complex anions is determined along the [\u22121 0 1] direction in the structure. Complex cations and crystallization water molecules are located between the mentioned layers.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0022476611040275", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1135923", 
        "issn": [
          "0022-4766", 
          "2542-0976"
        ], 
        "name": "Journal of Structural Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "52"
      }
    ], 
    "keywords": [
      "P21/c space group", 
      "crystallization water molecules", 
      "double complex salts", 
      "complex cations", 
      "complex anions", 
      "water molecules", 
      "complex salts", 
      "ray diffraction", 
      "crystal structure", 
      "space group", 
      "pseudohexagonal packing", 
      "single crystals", 
      "crystallographic characteristics", 
      "anions", 
      "\u00c53", 
      "cations", 
      "diffraction", 
      "salt", 
      "molecules", 
      "structure", 
      "packing", 
      "crystals", 
      "cm3", 
      "layer", 
      "Dx", 
      "group", 
      "characteristics", 
      "direction"
    ], 
    "name": "Crystal structure of [Pd(NH3)4]3[Ir(NO2)6]2\u00b7H2O", 
    "pagination": "816", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1038497827"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0022476611040275"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0022476611040275", 
      "https://app.dimensions.ai/details/publication/pub.1038497827"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:26", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_526.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0022476611040275"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0022476611040275'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0022476611040275'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0022476611040275'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0022476611040275'


 

This table displays all metadata directly associated to this object as RDF triples.

125 TRIPLES      21 PREDICATES      54 URIs      46 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0022476611040275 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N182d499147014cf8a3277ae44b5ea51f
4 schema:datePublished 2011-08
5 schema:datePublishedReg 2011-08-01
6 schema:description A single crystal of [Pd(NH3)4]3[Ir(NO2)6]2·H2O double complex salt is studied by X-ray diffraction. Crystallographic characteristics are as follows: a = 21.0335(5) Å, b = 8.0592(2) Å, c = 21.3452(5) Å, β = 91.254(1)°, V = 3617.43(15) Å3, P21/c space group, Z = 4, dx = 2.714 g/cm3. Single-layer pseudohexagonal packing of complex anions is determined along the [−1 0 1] direction in the structure. Complex cations and crystallization water molecules are located between the mentioned layers.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N8647bb97595747f6ba852dd6f6e8c3b3
11 Nf1f8202b78174b818b6285f2d1db993f
12 sg:journal.1135923
13 schema:keywords Dx
14 P21/c space group
15 anions
16 cations
17 characteristics
18 cm3
19 complex anions
20 complex cations
21 complex salts
22 crystal structure
23 crystallization water molecules
24 crystallographic characteristics
25 crystals
26 diffraction
27 direction
28 double complex salts
29 group
30 layer
31 molecules
32 packing
33 pseudohexagonal packing
34 ray diffraction
35 salt
36 single crystals
37 space group
38 structure
39 water molecules
40 Å3
41 schema:name Crystal structure of [Pd(NH3)4]3[Ir(NO2)6]2·H2O
42 schema:pagination 816
43 schema:productId N28223e67de6c4586a4dfa4bc76b02611
44 N4141aba913f04c92ad783d73c5653b62
45 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038497827
46 https://doi.org/10.1134/s0022476611040275
47 schema:sdDatePublished 2022-05-20T07:26
48 schema:sdLicense https://scigraph.springernature.com/explorer/license/
49 schema:sdPublisher Nac20c50b270b4c08b0207d5d255ee63e
50 schema:url https://doi.org/10.1134/s0022476611040275
51 sgo:license sg:explorer/license/
52 sgo:sdDataset articles
53 rdf:type schema:ScholarlyArticle
54 N11b6841c06c341688034ae4bd51f134f rdf:first sg:person.0713211235.58
55 rdf:rest Nfcfd92d4b70941afb5777e4543a2cc9b
56 N182d499147014cf8a3277ae44b5ea51f rdf:first sg:person.014144422711.19
57 rdf:rest N69176ba165ea4ebc906e5b6e6d5895df
58 N28223e67de6c4586a4dfa4bc76b02611 schema:name dimensions_id
59 schema:value pub.1038497827
60 rdf:type schema:PropertyValue
61 N4141aba913f04c92ad783d73c5653b62 schema:name doi
62 schema:value 10.1134/s0022476611040275
63 rdf:type schema:PropertyValue
64 N69176ba165ea4ebc906e5b6e6d5895df rdf:first sg:person.010367230757.12
65 rdf:rest Na6919ad289164ced822e915ce72cfd5c
66 N8647bb97595747f6ba852dd6f6e8c3b3 schema:volumeNumber 52
67 rdf:type schema:PublicationVolume
68 Na6919ad289164ced822e915ce72cfd5c rdf:first sg:person.0643531001.56
69 rdf:rest Ndb7f13badc8242098676f85e3a7e4cd6
70 Nac20c50b270b4c08b0207d5d255ee63e schema:name Springer Nature - SN SciGraph project
71 rdf:type schema:Organization
72 Ndb7f13badc8242098676f85e3a7e4cd6 rdf:first sg:person.012641166115.54
73 rdf:rest N11b6841c06c341688034ae4bd51f134f
74 Nf1f8202b78174b818b6285f2d1db993f schema:issueNumber 4
75 rdf:type schema:PublicationIssue
76 Nfcfd92d4b70941afb5777e4543a2cc9b rdf:first sg:person.015627070115.78
77 rdf:rest rdf:nil
78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
79 schema:name Chemical Sciences
80 rdf:type schema:DefinedTerm
81 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
82 schema:name Physical Chemistry (incl. Structural)
83 rdf:type schema:DefinedTerm
84 sg:journal.1135923 schema:issn 0022-4766
85 2542-0976
86 schema:name Journal of Structural Chemistry
87 schema:publisher Pleiades Publishing
88 rdf:type schema:Periodical
89 sg:person.010367230757.12 schema:affiliation grid-institutes:grid.425759.8
90 schema:familyName Shusharina
91 schema:givenName E. A.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010367230757.12
93 rdf:type schema:Person
94 sg:person.012641166115.54 schema:affiliation grid-institutes:grid.4605.7
95 schema:familyName Shubin
96 schema:givenName Yu. V.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012641166115.54
98 rdf:type schema:Person
99 sg:person.014144422711.19 schema:affiliation grid-institutes:grid.425759.8
100 schema:familyName Rybinskaya
101 schema:givenName A. A.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014144422711.19
103 rdf:type schema:Person
104 sg:person.015627070115.78 schema:affiliation grid-institutes:grid.4605.7
105 schema:familyName Gromilov
106 schema:givenName S. A.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015627070115.78
108 rdf:type schema:Person
109 sg:person.0643531001.56 schema:affiliation grid-institutes:grid.4605.7
110 schema:familyName Plyusnin
111 schema:givenName P. E.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0643531001.56
113 rdf:type schema:Person
114 sg:person.0713211235.58 schema:affiliation grid-institutes:grid.4605.7
115 schema:familyName Korenev
116 schema:givenName S. V.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0713211235.58
118 rdf:type schema:Person
119 grid-institutes:grid.425759.8 schema:alternateName A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
120 schema:name A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
121 rdf:type schema:Organization
122 grid-institutes:grid.4605.7 schema:alternateName Novosibirsk State University, Novosibirsk, Russia
123 schema:name A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
124 Novosibirsk State University, Novosibirsk, Russia
125 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...