Crystal structure of [Pd(NH3)4][Rh(NH3)(NO2)5] View Full Text


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Article Info

DATE

2011-06

AUTHORS

E. A. Shusharina, A. A. Rybinskaya, P. E. Plyusnin, Yu. V. Shubin, S. V. Korenev, S. A. Gromilov

ABSTRACT

An XRD analysis is used to study the single crystal of [Pd(NH3)4][Rh(NH3)(NO2)5] double complex salt at T = 150(2) K. Crystallographic characteristics are as follows: a = 7.6458(5) Å, b = 9.8813(6) Å, c = 9.5788(7) Å, β = 109.469(2)°, V = 682.30(8) Å3, P21/m space group, Z = 2, dx = 2.553 g/cm3. The geometry of the complex [Rh(NH3)(NO2)5]2− anion is described for the first time: Rh-N(NO2) distances are 2.020(4)–2.060(3) Å, Rh-N(NH3) 2.074(4) Å, N(NO2)-Rh-N(NH3) trans-angle is 178.8(2)°. More... »

PAGES

621

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476611030255

DOI

http://dx.doi.org/10.1134/s0022476611030255

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009524342


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