A new square niobium cluster {Nb4(μ4-O)I8}2+. Crystal structure of a [Nb4OI8][Mo6I14]2∞ polymer View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-04

AUTHORS

S. B. Artemkina, N. G. Naumov, A. V. Virovets, S. G. Kozlova, V. E. Fedorov

ABSTRACT

A crystal structure of a new layered [Nb4OI8][Mo6I14]2∞ polymer containing a previously unknown niobium cluster {Nb4(μ4-O)I8}2+ with a μ4 oxygen atom is determined. The compound crystallizes in the P triclinic space group with unit cell parameters a = 10.1842(6) Å, b = 10.1880(6) Å, c = 11.5700(6) Å, α = 78.058(2)°, β = 77.944(2)°, γ = 80.738(2)°, V = 1139.85(11) Å3, Z = 1, Rf = 0.0414. The electronic structure of the [{Nb4(μ4-O)I8}I4]2− cluster complex is calculated. More... »

PAGES

389-394

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0022476611020211

DOI

http://dx.doi.org/10.1134/s0022476611020211

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013182715


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