Ontology type: schema:ScholarlyArticle
2018-10
AUTHORSP. S. Savchenkov, E. A. Goremychkin, V. V. Popov, B. L. Shapir, P. A. Borisova, A. A. Yastrebtsev, B. R. Gaynanov, M. P. Krasnov, A. P. Menushenkov, P. A. Alekseev
ABSTRACTThe formation of the structural and dynamic properties of La2Zr2O7 in the process of crystallization at the isothermal annealing of initially amorphous precursors obtained by the coprecipitation of corresponding salts has been studied by neutron spectroscopy. The existence of vibrational states characteristic of hydrogen, which is in one or another of the possible chemical states and is incorporated into a solid matrix, has been detected in the spectra of amorphous and fluorite phases. The DFT calculation of the phonon density of states has been performed to analyze the energy structure of experimental phonon spectra for various phases of the La2Zr2O7 compound. The amount of hydrogen in the fluorite phase has been estimated. More... »
PAGES532-536
http://scigraph.springernature.com/pub.10.1134/s0021364018200134
DOIhttp://dx.doi.org/10.1134/s0021364018200134
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