Optically induced structural transformation in disordered kesterite Cu2ZnSnS4 View Full Text


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Article Info

DATE

2013-11-07

AUTHORS

M. Ya. Valakh, V. M. Dzhagan, I. S. Babichuk, X. Fontane, A. Perez-Rodriquez, S. Schorr

ABSTRACT

The kesterite-structured semiconductor Cu2ZnSnS4 is one of the most promising compound for earth-abundant low-cost solar cells. One of the complex problem on this way deals with its stoichiometry. In this work Raman spectra of Cu-rich Cu2ZnSnS4 crystals are discussed in connection with the non-stoichiometric composition and disordering within the cation sublattice of the kesterite. The shift of the main A-peak from 338 to 331 cm−1 and its broadening are attributed here to transition from the kesterite (I\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$\bar 4$\end{document} symmetry) to the disordered kesterite structure (I\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$\bar 4$\end{document} 2m symmetry). It is shown that this transition may also be driven by an intense light, which could stimulate transformation of Cu+-ion to Cu2+-ions and facilitates generation of CuZn-defects on 2d-crystalographic positions. More... »

PAGES

255-258

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0021364013180136

DOI

http://dx.doi.org/10.1134/s0021364013180136

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014984919


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