Features of the local structure of rare-earth dodecaborides RB12 (R = Ho, Er, Tm, Yb, Lu) View Full Text


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Article Info

DATE

2013-10-11

AUTHORS

A. P. Menushenkov, A. A. Yaroslavtsev, I. A. Zaluzhnyy, A. V. Kuznetsov, R. V. Chernikov, N. Yu. Shitsevalova, V. B. Filippov

ABSTRACT

The parameters of the local crystal structure of dodecaborides RB12 (R = Ho, Er, Tm, Yb, Lu) have been determined by extended X-ray absorption fine structure (EXAFS) spectroscopy. It has been shown that the vibrations of the rare-earth ion with respect to the boron cage are well described in the harmonic approximation. At the same time, the displacement of rare-earth ions from equilibrium positions of the crystal structure should be taken into account to determine the length of the R-B bond. The analysis of EXAFS spectra has revealed the displacement of 1–6% of rare-earth ions by about 0.2–0.3 Å in all compounds under investigation; this displacement at low temperatures results in the formation of a cage glass phase. More... »

PAGES

165-169

References to SciGraph publications

  • 2010-08. Isotope effect in charge transport of LuB12 in JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS
  • 2011-09. Effects of disorder and isotopic substitution in the specific heat and Raman scattering in LuB12 in JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS
  • 2012-12-21. Superconductivity in ZrB12 and LuB12 with Various Boron Isotopes in JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM
  • 2009-04. Anomalies of magnetoresistance of compounds with atomic clusters RB12 (R = Ho, Er, Tm, Lu) in JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS
  • 1998-06. Anharmonicity and superconductivity in Ba0.6K0.4BiO3 in JETP LETTERS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s002136401316011x

    DOI

    http://dx.doi.org/10.1134/s002136401316011x

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1022369677


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