Phase relations in M2IO-P2O5-Fe2O3-CaO(CaF2) (MI = Na, K) high-temperature solutions and the structure of Na2.5CaFe1.5(PO4)3 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-06-08

AUTHORS

N. Yu. Strutynska, Ya. Yu. Kovba, I. V. Zatovsky, V. N. Baumer, I. V. Ogorodnyk, N. S. Slobodyanik

ABSTRACT

Phase relations in high-temperature solutions of the M2IO-P2O5-Fe2O3-CaO(CaF2) (MI = Na, K) systems (M2IO/P2O5 = 0.7, 1.0, 1.3; Ca/P = 0.3; Ca/Fe = 1.0; Δt = 1000–680°C) have been studied. The nature of the calcium precursor has been shown to influence the phase relations in the multicomponent alkali metal phosphate high-temperature solutions. The synthesized compounds have been characterized by X-ray powder diffraction and IR spectroscopy, and the crystal structure of the new phosphate Na2.5CaFe1.5(PO4)3 has been determined by single-crystal X-ray structure analysis. More... »

PAGES

709-714

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0020168513060150

DOI

http://dx.doi.org/10.1134/s0020168513060150

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047167764


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