Ontology type: schema:ScholarlyArticle
2013-06
AUTHORSN. A. Ovchinnikova, E. A. Martynova, N. A. Minaeva, O. G. Ellert
ABSTRACTReactions of the higher molybdenum and tungsten chlorides with phenyl isothiocyanate or with N, N′-dicyclohexylcarbodiimide and carbon dioxide in dichloroethane are the first to demonstrate the possibility of insertion of carbon dioxide in combination with other heterocumulenes into transition metal-halogen bonds. IR spectroscopy and elemental analysis data show that the reactions result in the attachment of the ligands at the same metal-chlorine bond and the formation of heteromolecular insertion products with the compositions and where x = 4 and 5 for the Mo and W derivatives, respectively. More... »
PAGES638-642
http://scigraph.springernature.com/pub.10.1134/s0020168513050105
DOIhttp://dx.doi.org/10.1134/s0020168513050105
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