Synthesis of carboxylate derivatives of molybdenum and tungsten based on joint insertion of CO2 and PhNCS or N, N′-dicyclohexylcarbodiimide into ... View Full Text


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Article Info

DATE

2013-06

AUTHORS

N. A. Ovchinnikova, E. A. Martynova, N. A. Minaeva, O. G. Ellert

ABSTRACT

Reactions of the higher molybdenum and tungsten chlorides with phenyl isothiocyanate or with N, N′-dicyclohexylcarbodiimide and carbon dioxide in dichloroethane are the first to demonstrate the possibility of insertion of carbon dioxide in combination with other heterocumulenes into transition metal-halogen bonds. IR spectroscopy and elemental analysis data show that the reactions result in the attachment of the ligands at the same metal-chlorine bond and the formation of heteromolecular insertion products with the compositions and where x = 4 and 5 for the Mo and W derivatives, respectively. More... »

PAGES

638-642

References to SciGraph publications

Journal

TITLE

Inorganic Materials

ISSUE

6

VOLUME

49

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0020168513050105

DOI

http://dx.doi.org/10.1134/s0020168513050105

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1053513594


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