Synthesis and properties of Sr1 − xMxCo0.8 − yAlyFe0.2O3 − z perovskite-like oxides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-10

AUTHORS

E. B. Pyatiletova, A. P. Nemudry, N. Z. Lyakhov

ABSTRACT

Partial isomorphous substitutions on the strontium and cobalt sites in the SrCo0.8Fe0.2O3 − z perovskite have been shown to have a significant effect on its properties. Aluminum substitution for cobalt suppresses the brownmillerite-perovskite structural phase transition, stabilizes the cubic perovskite structure in a wide range of oxygen stoichiometries, and markedly enhances the thermal stability of the material in reducing atmospheres, without reducing the oxygen mobility. Partial lanthanum and calcium substitutions for strontium lead to the formation of Sr1 − xMxCo0.5Al0.3Fe0.2O3 − z (M = La, Ca) perovskite-like oxides, which have cubic and orthorhombic structures, respectively. The Sr1 − xLaxCo0.5Al0.3Fe0.2O3 − z perovskites possess high chemical stability in reducing atmospheres and are potentially attractive as materials for oxygen-permeable membranes of catalytic methane-to-syngas conversion reactors. More... »

PAGES

1134-1141

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0020168507100184

DOI

http://dx.doi.org/10.1134/s0020168507100184

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032603263


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