Determination of the quantum yield of singlet oxygen sensitized by halogenated boron difluoride dipyrromethenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-05-23

AUTHORS

R. T. Kuznetsova, Iu. V. Aksenova, D. E. Bashkirtsev, A. S. Shulev, E. V. Antina, M. B. Berezin, N. A. Bumagina

ABSTRACT

The spectral–luminescent, photophysical, and photochemical properties of dichloro-, dibromo-, and diiodo-derivatives of boron dipyrromethenate (BODIPY) have been studied, as well as the feasibility of generating singlet oxygen (1O2) via its photosensitization by the dihalogenated derivatives of BF2 dipyrromethene in solutions. Quantum yields of singlet oxygen have been determined using 1,3-diphenylisobenzofuran as the 1O2 trap. The lowest fluorescence quantum yields have been shown to correspond to the maximum yields of singlet oxygen. It has been found that the best 1O2 photosensitizer among the three test dihalotetraphenylaza- BODIPY is dibromotetraphenylaza-BODIPY, which in addition possesses the highest photostability. Diiodotetramethyl-BODIPY results in the singlet oxygen yield close to unity, but it has significantly lower photostability. The yield of singlet oxygen is affected by the solvent. Dibromtetraphenylaza-BODIPY and diiodotetramethyl-BODIPY may find use as a medium in photodynamic therapy and photocatalysis of oxidation reactions. More... »

PAGES

175-181

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0018143917030079

DOI

http://dx.doi.org/10.1134/s0018143917030079

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1085562076


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