Effect of multiply charged paramagnetic metal cations on J-aggregation of thiacyanine dyes View Full Text


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Article Info

DATE

2011-03

AUTHORS

A. D. Nekrasov, B. I. Shapiro

ABSTRACT

J-Aggregation of thiacyanine dyes with a different length of the polymethine chain has been studied in aqueous solutions in the presence of paramagnetic metal cations. The introduction of multiply charged metal cations stimulates J-aggregation. The number of molecules involved in the composition of J-aggregates has been calculated to be four on the basis of analysis of the absorption spectra. The equilibrium constants and the thermodynamic parameters of J-aggregation have been determined. The effect of the dye structure and the metal cation nature on J-aggregation has been revealed. More... »

PAGES

133-139

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s001814391102010x

DOI

http://dx.doi.org/10.1134/s001814391102010x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005413824


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