Solid-State Catalytic Isotope Exchange of Hydrogen for Deuterium in Cyclopropylglycine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-07

AUTHORS

A. K. Dadayan, Yu. A. Borisov, E. V. Bocharov, Yu. A. Zolotarev, I. Yu. Nagaev, N. F. Myasoedov

ABSTRACT

The reaction of spillover hydrogen (SH) with cyclopropylglycine (cPG) in high-temperature solid-state catalytic hydrogen isotope exchange (HTCIE) has been studied experimentally and using density functional theory (DFT). NMR spectroscopy and mass spectrometry have shown a high regioselectivity and stereoselectivity for the reaction of spillover hydrogen with cPG fragments. The Gly fragment has been shown to be the most reactive in HTCIE, for which high stereoselectivity of substitution of hydrogen by deuterium has been demonstrated. More... »

PAGES

15-19

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0012501619010056

DOI

http://dx.doi.org/10.1134/s0012501619010056

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1113204489


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Molecular Genetics, Russian Academy of Sciences, 123182, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dadayan", 
        "givenName": "A. K.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Borisov", 
        "givenName": "Yu. A.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow Institute of Physics and Technology", 
          "id": "https://www.grid.ac/institutes/grid.18763.3b", 
          "name": [
            "Russian Research Center \u201cKurchatov Institute\u201d, 123182, Moscow, Russia", 
            "Shemyakin\u2013Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, 117997, Moscow, Russia", 
            "Moscow Institute of Physics and Technology (State University), 141700, Dolgoprudnyi, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bocharov", 
        "givenName": "E. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Molecular Genetics, Russian Academy of Sciences, 123182, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zolotarev", 
        "givenName": "Yu. A.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Molecular Genetics, Russian Academy of Sciences, 123182, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nagaev", 
        "givenName": "I. Yu.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Molecular Genetics, Russian Academy of Sciences, 123182, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Myasoedov", 
        "givenName": "N. F.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0167-2991(97)80840-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038171431"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0009-2614(82)85052-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043206739"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/ft9959101539", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046956323"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr100053w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053761533"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr100053w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053761533"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr00035a014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054068567"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100377a021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055668015"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp4015299", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056094176"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-07", 
    "datePublishedReg": "2019-07-01", 
    "description": "The reaction of spillover hydrogen (SH) with cyclopropylglycine (cPG) in high-temperature solid-state catalytic hydrogen isotope exchange (HTCIE) has been studied experimentally and using density functional theory (DFT). NMR spectroscopy and mass spectrometry have shown a high regioselectivity and stereoselectivity for the reaction of spillover hydrogen with cPG fragments. The Gly fragment has been shown to be the most reactive in HTCIE, for which high stereoselectivity of substitution of hydrogen by deuterium has been demonstrated.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0012501619010056", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1083525", 
        "issn": [
          "0012-5016", 
          "1608-3121"
        ], 
        "name": "Doklady Physical Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "484"
      }
    ], 
    "name": "Solid-State Catalytic Isotope Exchange of Hydrogen for Deuterium in Cyclopropylglycine", 
    "pagination": "15-19", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0012501619010056"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "1510c835da44cb66eb9854b25ccfc9253acac03e274fd26489a7e16084f088db"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1113204489"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0012501619010056", 
      "https://app.dimensions.ai/details/publication/pub.1113204489"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-15T09:14", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000376_0000000376/records_56164_00000006.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1134%2FS0012501619010056"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0012501619010056'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0012501619010056'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0012501619010056'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0012501619010056'


 

This table displays all metadata directly associated to this object as RDF triples.

117 TRIPLES      21 PREDICATES      34 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0012501619010056 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nd1cb21ff947f43bfa1890683d6e8a8ee
4 schema:citation https://doi.org/10.1016/0009-2614(82)85052-5
5 https://doi.org/10.1016/s0167-2991(97)80840-3
6 https://doi.org/10.1021/cr00035a014
7 https://doi.org/10.1021/cr100053w
8 https://doi.org/10.1021/j100377a021
9 https://doi.org/10.1021/jp4015299
10 https://doi.org/10.1039/ft9959101539
11 schema:datePublished 2019-07
12 schema:datePublishedReg 2019-07-01
13 schema:description The reaction of spillover hydrogen (SH) with cyclopropylglycine (cPG) in high-temperature solid-state catalytic hydrogen isotope exchange (HTCIE) has been studied experimentally and using density functional theory (DFT). NMR spectroscopy and mass spectrometry have shown a high regioselectivity and stereoselectivity for the reaction of spillover hydrogen with cPG fragments. The Gly fragment has been shown to be the most reactive in HTCIE, for which high stereoselectivity of substitution of hydrogen by deuterium has been demonstrated.
14 schema:genre research_article
15 schema:inLanguage en
16 schema:isAccessibleForFree false
17 schema:isPartOf N0fbf52550fdb4a6e8d88218b12bbabcb
18 N1907d6cc355642399b1e6bc4bd403bc6
19 sg:journal.1083525
20 schema:name Solid-State Catalytic Isotope Exchange of Hydrogen for Deuterium in Cyclopropylglycine
21 schema:pagination 15-19
22 schema:productId N2c0c590081e44341805c7db72c9ccfc4
23 N432a5a8ca1024dafbe800a7bc6ec99b5
24 N47eb1642f3474b06aee6edf65000d455
25 schema:sameAs https://app.dimensions.ai/details/publication/pub.1113204489
26 https://doi.org/10.1134/s0012501619010056
27 schema:sdDatePublished 2019-04-15T09:14
28 schema:sdLicense https://scigraph.springernature.com/explorer/license/
29 schema:sdPublisher N3fbc690f53ed42aaacc2266022eceebf
30 schema:url https://link.springer.com/10.1134%2FS0012501619010056
31 sgo:license sg:explorer/license/
32 sgo:sdDataset articles
33 rdf:type schema:ScholarlyArticle
34 N0fbf52550fdb4a6e8d88218b12bbabcb schema:issueNumber 1
35 rdf:type schema:PublicationIssue
36 N16731fca4b194bf483fcdb313cc42534 rdf:first N1bfd459b389a4315ad02633041374624
37 rdf:rest N7ecdcdb3ea8c49b487364ee7fbd656c8
38 N1907d6cc355642399b1e6bc4bd403bc6 schema:volumeNumber 484
39 rdf:type schema:PublicationVolume
40 N1bfd459b389a4315ad02633041374624 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
41 schema:familyName Nagaev
42 schema:givenName I. Yu.
43 rdf:type schema:Person
44 N1f4eccb0823145289ace8692b4de77a4 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
45 schema:familyName Borisov
46 schema:givenName Yu. A.
47 rdf:type schema:Person
48 N27096ca380c34a82a091a8185e7498c2 rdf:first N55d6d8643d4c4b968677f25e40284bde
49 rdf:rest Ne3a59380122c4d8995552c014e25ff04
50 N2c0c590081e44341805c7db72c9ccfc4 schema:name readcube_id
51 schema:value 1510c835da44cb66eb9854b25ccfc9253acac03e274fd26489a7e16084f088db
52 rdf:type schema:PropertyValue
53 N3fbc690f53ed42aaacc2266022eceebf schema:name Springer Nature - SN SciGraph project
54 rdf:type schema:Organization
55 N432a5a8ca1024dafbe800a7bc6ec99b5 schema:name dimensions_id
56 schema:value pub.1113204489
57 rdf:type schema:PropertyValue
58 N47eb1642f3474b06aee6edf65000d455 schema:name doi
59 schema:value 10.1134/s0012501619010056
60 rdf:type schema:PropertyValue
61 N55d6d8643d4c4b968677f25e40284bde schema:affiliation https://www.grid.ac/institutes/grid.18763.3b
62 schema:familyName Bocharov
63 schema:givenName E. V.
64 rdf:type schema:Person
65 N5f27b652178644889db684abdf9596e1 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
66 schema:familyName Dadayan
67 schema:givenName A. K.
68 rdf:type schema:Person
69 N7ecdcdb3ea8c49b487364ee7fbd656c8 rdf:first N8775b605b0634acfbdf7292769d2edf7
70 rdf:rest rdf:nil
71 N8775b605b0634acfbdf7292769d2edf7 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
72 schema:familyName Myasoedov
73 schema:givenName N. F.
74 rdf:type schema:Person
75 N9769ab6945524a1c9cac5192e365a16b schema:affiliation https://www.grid.ac/institutes/grid.4886.2
76 schema:familyName Zolotarev
77 schema:givenName Yu. A.
78 rdf:type schema:Person
79 Nd1cb21ff947f43bfa1890683d6e8a8ee rdf:first N5f27b652178644889db684abdf9596e1
80 rdf:rest Ne5909bd4147d43df9daaf2828e1ec576
81 Ne3a59380122c4d8995552c014e25ff04 rdf:first N9769ab6945524a1c9cac5192e365a16b
82 rdf:rest N16731fca4b194bf483fcdb313cc42534
83 Ne5909bd4147d43df9daaf2828e1ec576 rdf:first N1f4eccb0823145289ace8692b4de77a4
84 rdf:rest N27096ca380c34a82a091a8185e7498c2
85 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
86 schema:name Chemical Sciences
87 rdf:type schema:DefinedTerm
88 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
89 schema:name Physical Chemistry (incl. Structural)
90 rdf:type schema:DefinedTerm
91 sg:journal.1083525 schema:issn 0012-5016
92 1608-3121
93 schema:name Doklady Physical Chemistry
94 rdf:type schema:Periodical
95 https://doi.org/10.1016/0009-2614(82)85052-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043206739
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/s0167-2991(97)80840-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038171431
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1021/cr00035a014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054068567
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1021/cr100053w schema:sameAs https://app.dimensions.ai/details/publication/pub.1053761533
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1021/j100377a021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055668015
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1021/jp4015299 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056094176
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1039/ft9959101539 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046956323
108 rdf:type schema:CreativeWork
109 https://www.grid.ac/institutes/grid.18763.3b schema:alternateName Moscow Institute of Physics and Technology
110 schema:name Moscow Institute of Physics and Technology (State University), 141700, Dolgoprudnyi, Moscow oblast, Russia
111 Russian Research Center “Kurchatov Institute”, 123182, Moscow, Russia
112 Shemyakin–Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, 117997, Moscow, Russia
113 rdf:type schema:Organization
114 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
115 schema:name Institute of Molecular Genetics, Russian Academy of Sciences, 123182, Moscow, Russia
116 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
117 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...