Stereoisomerism of Octahedral Titanium cis-Tetrafluoro Complexes with Ph2P(O)CH2CH(OH)Me Enantiomers According to 19F NMR Data View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-10

AUTHORS

E. G. Il’in, A. S. Parshakov, V. V. Danilov, E. I. Goryunov, E. E. Nifant’ev

ABSTRACT

Effect of enantiomers of a monodentate ligand on the stereoisomerism of mixed octahedral cis-tetrafluoro complexes of d0 transition metals has been studied by 19F{1H} and 31P{1H} NMR by the example of TiF4 complexation in CH2Cl2 with Ph2P(O)CH2CH(OH)Me (L) containing asymmetric carbon atom in the aliphatic hydrocarbon group that constitutes a racemic mixture of enantiomers. Composition of complexes formed in solution has been determined, conclusion has been drawn on the relative stereochemical configuration of the chiral and meso stereoisomers of octahedral complex cis-TiF4L2 on the basis of analysis of 19F NMR spectra, using the heterotropism concept. More... »

PAGES

135-139

Journal

TITLE

Doklady Physical Chemistry

ISSUE

2

VOLUME

482

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0012501618110015

DOI

http://dx.doi.org/10.1134/s0012501618110015

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1109764783


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